MnO2-Au Composite Electrodes for Supercapacitors

被引:11
作者
Dai, Yuming [1 ,2 ,3 ]
Tang, Shaochun [2 ,3 ]
Wang, Xiaoyu [1 ]
Huang, Xiang [1 ]
Zhu, Chao [1 ]
Hang, Zusheng [1 ]
Meng, Xiangkang [2 ,3 ]
机构
[1] Nanjing Inst Technol, Sch Mat Engn, Nanjing, Jiangsu, Peoples R China
[2] Nanjing Univ, Inst Mat Engn, Natl Lab Solid State Microstruct, Nanjing, Jiangsu, Peoples R China
[3] Nanjing Univ, Coll Engn & Appl Sci, Nanjing, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
MANGANESE; CAPACITOR; STORAGE;
D O I
10.1246/cl.130819
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The MnO2 nanorod-Au nanoparticle composites that exhibit superior supercapacitance and long-term durability have been fabricated using a two-step procedure. The role of Au nanoparticles is not only to improve the electrical conductivity but also to enhance the structural stability. The composites have a specific capacitance of 406.8 F g(-1) at a scan rate of 50 mV s(-1), which is almost five times that of the pure MnO2 nanorods. The composites have 91.3% capacitance retention over 2000 charge-discharge cycles at 5 A g(-1), which is much better than the capacitance retention of pure MnO2 nanorods (74.6%).
引用
收藏
页码:122 / 124
页数:3
相关论文
共 14 条
  • [1] Flexible Zn2SnO4/MnO2 Core/Shell Nanocable-Carbon Microfiber Hybrid Composites for High-Performance Supercapacitor Electrodes
    Bao, Lihong
    Zang, Jianfeng
    Li, Xiaodong
    [J]. NANO LETTERS, 2011, 11 (03) : 1215 - 1220
  • [2] Ultracapacitors: why, how, and where is the technology
    Burke, A
    [J]. JOURNAL OF POWER SOURCES, 2000, 91 (01) : 37 - 50
  • [3] High-performance supercapacitor material based on Ni(OH)2 nanowire-MnO2 nanoflakes core-shell nanostructures
    Jiang, Hao
    Li, Chunzhong
    Sun, Ting
    Ma, Jan
    [J]. CHEMICAL COMMUNICATIONS, 2012, 48 (20) : 2606 - 2608
  • [4] Recent Advances in Metal Oxide-based Electrode Architecture Design for Electrochemical Energy Storage
    Jiang, Jian
    Li, Yuanyuan
    Liu, Jinping
    Huang, Xintang
    Yuan, Changzhou
    Lou, Xiong Wen
    [J]. ADVANCED MATERIALS, 2012, 24 (38) : 5166 - 5180
  • [5] Nanoporous metal/oxide hybrid electrodes for electrochemical supercapacitors
    Lang, Xingyou
    Hirata, Akihiko
    Fujita, Takeshi
    Chen, Mingwei
    [J]. NATURE NANOTECHNOLOGY, 2011, 6 (04) : 232 - 236
  • [6] Cu2O@reduced graphene oxide composite for removal of contaminants from water and supercapacitors
    Li, Baojun
    Cao, Huaqiang
    Yin, Gui
    Lu, Yuexiang
    Yin, Jiefu
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (29) : 10645 - 10648
  • [7] A novel concept of hybrid capacitor based on manganese oxide materials
    Ma, Sang-Bok
    Nam, Kyung-Wan
    Yoon, Won-Sub
    Yang, Xiao-Qing
    Ahn, Kyun-Young
    Oh, Ki-Hwan
    Kim, Kwang-Bum
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (12) : 2807 - 2811
  • [8] Controlled synthesis of ε-MnO2 and its application in hybrid supercapacitor devices
    Roberts, Alexander J.
    Slade, Robert C. T.
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (16) : 3221 - 3226
  • [9] Charge storage mechanism of MnO2 electrode used in aqueous electrochemical capacitor
    Toupin, M
    Brousse, T
    Bélanger, D
    [J]. CHEMISTRY OF MATERIALS, 2004, 16 (16) : 3184 - 3190
  • [10] A review of electrode materials for electrochemical supercapacitors
    Wang, Guoping
    Zhang, Lei
    Zhang, Jiujun
    [J]. CHEMICAL SOCIETY REVIEWS, 2012, 41 (02) : 797 - 828