Application of Modified with Copper Porous Carbon Matrix on Lead-Acid Battery

被引:10
作者
Wrobel, Kamil [1 ]
Czerwinski, Andrzej [2 ,3 ]
机构
[1] Ind Chem Res Inst, Rydygiera 8, PL-01793 Warsaw, Poland
[2] Warsaw Univ, Fac Chem, Pasteura 1, PL-02093 Warsaw, Poland
[3] Univ Warsaw, Biol & Chem Res Ctr, Zwirki & Wigury 101, PL-02089 Warsaw, Poland
来源
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2016年 / 11卷 / 11期
关键词
lead-acid battery; negative plate; carbon matrix; copper-lead; RETICULATED VITREOUS CARBON; ELECTROCHEMICAL-BEHAVIOR; CURRENT COLLECTORS; FOAM GRIDS; NEGATIVE ELECTRODE; VRLA BATTERY; PERFORMANCE; CARRIER;
D O I
10.20964/2016.11.67
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Negative plates for the lead-acid battery with porous carbon grids coated with cooper or copper and lead have been prepared and tested. In the first stage of the study a method of galvanic coating of the porous carbon matrix was developed. Analysis of the quality of the metal coatings was based on the results obtained with a scanning electron microscope. Measurement of the electrical conductivity for a series of collectors modified with various metal layers was also performed. Additionally, for the carbon matrix modified with a double metal layer of 20 mu m Cu and 20 mu m Pb a series of electrochemical measurements using cyclic voltammetry was performed to investigate its electrochemical properties and compared with a solid lead electrode. In the study a series of experimental cells was prepared in which the negative plate collector used: an unmodified carbon matrix, a carbon matrix modified with lead or copper and a carbon matrix modified with double metal, copper-lead layer.
引用
收藏
页码:8927 / 8937
页数:11
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