Investigation on the modification behavior of A356 alloy inoculated with a Sr-Y composite modifier

被引:22
作者
Dong Yun [1 ]
Zheng Runguo [1 ]
Lin Xiaoping [1 ]
Ye Jie [1 ]
Sun Ling
机构
[1] Northeast Univ, Sch Met & Mat, Shenyang 110819, Peoples R China
基金
中国国家自然科学基金;
关键词
eutectic Si; composite modifier; degree of supercooling; rare earths; AL; MICROSTRUCTURE; REFINEMENT; PHASE;
D O I
10.1016/S1002-0721(12)60259-2
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In the present paper, differential scanning calorimetry (DSC), scanning electron microscopy (SEM), and X-ray diffraction (XRD) were used to examine the effects of a Sr-Y composite modifier on the microstructure of A356 alloy. After adding Y to A356, YAl3 compounds formed, and the size of the alpha (Al) crystal nucleus increased. The degree of supercooling caused by Sr-Y composite modifier was higher than Sr modification by 2.7 degrees C, leading to an increased nucleation rate. This increase in supercooling temperature was favorable to the refinement of eutectic structure of the alloy and its eutectic reaction was delayed to the maximum extent. The Si phase in the as-cast Sr-Y composite-modified A356 alloy was either granular or flaky. No large flakes of eutectic Si were found, and the modification effects were completely comparable with those obtained using a lone Sr modifier. After T6 heat treatment, most of the eutectic Si showed a grain-like shape with smaller grains. No eutectic Si with long-strip shapes, significant enhancements in the particle roundness and evenness of the Si crystals, and increased globosity were observed. Both the roundness and evenness of the grained Si crystals were enhanced, and the amount of globular eutectic Si available increased, these findings showed that excellent modification effects were achieved.
引用
收藏
页码:204 / 208
页数:5
相关论文
共 17 条
[1]   Ternary rare-earth alumo-silicides - single-crystal growth from Al flux, structural and physical properties [J].
Bobev, S ;
Tobash, PH ;
Fritsch, V ;
Thompson, JD ;
Hundley, MF ;
Sarrao, JL ;
Fisk, Z .
JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (06) :2091-2103
[2]   Refinement of cast microstructure of hypereutectic Al-Si alloys through the addition of rare earth metals [J].
Chang, JY ;
Moon, IG ;
Choi, CS .
JOURNAL OF MATERIALS SCIENCE, 1998, 33 (20) :5015-5023
[3]  
Gary W B, 1988, MOD CAST, V1, P52
[4]  
Guo Y J, 2007, J INNER MONGOLIA U T, V26, P21
[5]  
[韩剑 HAN Jian], 2009, [材料工程, Journal of Materials Engineering], P67
[6]  
Haque M M, 1995, MAT PROEESS TECHNOL, V55, P193
[7]   Refinement of eutectic silicon phase of aluminum A356 alloy using high-intensity ultrasonic vibration [J].
Jian, X ;
Meek, TT ;
Han, Q .
SCRIPTA MATERIALIA, 2006, 54 (05) :893-896
[8]  
Liao H C, 2000, CHIN J NONFERROUS ME, V5, P640
[9]  
[刘政 Liu Zheng], 2007, [特种铸造及有色合金, Special Casting & Non-ferrous Alloys], V27, P271
[10]  
[刘政 LIU Zheng], 2008, [铸造, Foundry], V57, P596