Synthesis, crystal structure, and luminescent property of [Zn2(Ox)3]H2L • 4H2O (L=2,2′-(1,4-butanediyl-bis(1H-benzimidazole))

被引：0

作者：

Gou, L. ^{[1
]}

Zhang, H. X. ^{[1
]}

Fan, X. Y. ^{[1
]}

Li, D. L. ^{[1
]}

机构：

[1] Changan Univ, Sch Mat Sci & Engn, Xian 710061, Shaanxi, Peoples R China

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 38卷 / 09期

基金：

中国国家自然科学基金;

关键词：

OXALATE COORDINATION POLYMERS; MAGNETIC-PROPERTIES; COMPLEXES; FRAMEWORK; TEMPLATES; LIGANDS; 1D; 2D;

D O I：

10.1134/S1070328412080052

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new complex [Zn-2(Ox)(3)]H2L center dot 4H(2)O (L = 2,2'-(1,4-butanediyl)-bis(1H-benzimidazole)) (I) has been hydrothermally synthesized and characterized by the elemental analysis, IR spectroscopy, and single crystal X-ray diffraction. It crystallizes in monoclinic space group P2(1)/c with a = 10.108(2), b = 15.600(4), c = 9.768(2) , beta = 105.289(3)center dot, V = 1485.7(6) (3), Z = 4. Complex I is a 2D honeycomb-like polymer with pro-toned L and water molecules intercalating in the cavities. The luminescent spectra shows the emission peak of complex I is at 455 nm which is attributed to ligand-to-metal charge transfer.

引用

页码：609 / 613

页数：5

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