Adsorption of Cr (VI) oxyanions onto modified wood pulp

被引:33
作者
Abdel-Halim, ES [1 ]
Abou-Okeil, A [1 ]
Hashem, A [1 ]
机构
[1] Natl Res Ctr, Text Res Div, Cairo, Egypt
关键词
Cr (VI) oxyanion; wood pulp; adsorption isotherm;
D O I
10.1080/03602550500373519
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A new adsorbent was prepared from wood pulp (WP) after reaction with epichlorohydrin and dimethylamine in the presence of pyridine and N,N-dimethylformamide (DMF). The adsorption of Cr (VI) from aqueous solutions by the so-prepared wood pulp adsorbent (WP-A) was investigated. Various factors affecting adsorption, such as pH, adsorbent concentration (1-5 g/L), agitation time (5-60 min), and Cr (VI) concentration (50-700), were taken into consideration. The adsorption of Cr (VI) onto (WP-A) was found to be pH-dependent and maximum adsorption was obtained at pH 3. The adsorption data obeyed Langmuir and Freundlich adsorption isotherms. The Langmuir adsorption capacity (Q(max)) was found to be 588.24 mg/g. Freundlich constants, K-F and n, were found to be 55.03 and 2.835, respectively.
引用
收藏
页码:71 / 76
页数:6
相关论文
共 30 条
  • [1] Investigation of removal of Cr(VI), Mo(VI), W(VI), V(IV), and V(V) oxy-ions from industrial waste-waters by adsorption and electrosorption at high-area carbon cloth
    Afkhami, A
    Conway, BE
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 251 (02) : 248 - 255
  • [2] EVALUATION OF METABOLIC END-POINTS OF ACUTE CYTOTOXICITY IN V79-FIBROBLASTS
    ANDREOLI, T
    DALDEGAN, B
    DEANGELIS, I
    FORTUNATI, E
    REGGIANI, D
    BIANCHI, V
    TIOZZO, R
    ZUCCO, F
    [J]. TOXICOLOGY IN VITRO, 1991, 5 (5-6) : 549 - 553
  • [3] Cr(VI) removal from synthetic wastewater using coconut shell charcoal and commercial activated carbon modified with oxidizing agents and/or chitosan
    Babel, S
    Kurniawan, TA
    [J]. CHEMOSPHERE, 2004, 54 (07) : 951 - 967
  • [4] Studies on enhancement of Cr(VI) biosorption by chemically modified biomass of Rhizopus nigricans
    Bai, RS
    Abraham, TE
    [J]. WATER RESEARCH, 2002, 36 (05) : 1224 - 1236
  • [5] Comparative study of adsorption properties of Turkish fly ashes II. The case of chromium (VI) and cadmium (II)
    Bayat, B
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2002, 95 (03) : 275 - 290
  • [6] EFFECT OF CHROMIUM ON SEED-GERMINATION, SEEDLING GROWTH AND YIELD OF PEAS
    BISHNOI, NR
    DUA, A
    GUPTA, VK
    SAWHNEY, SK
    [J]. AGRICULTURE ECOSYSTEMS & ENVIRONMENT, 1993, 47 (01) : 47 - 57
  • [7] Adsorption of Cr(VI) on activated rice husk carbon and activated alumina
    Bishnoi, NR
    Bajaj, M
    Sharma, N
    Gupta, A
    [J]. BIORESOURCE TECHNOLOGY, 2004, 91 (03) : 305 - 307
  • [8] LIQUID MEMBRANE MULTIPLE EMULSION PROCESS OF CHROMIUM(VI) SEPARATION FROM WASTE-WATERS
    CHAKRAVARTI, AK
    CHOWDHURY, AK
    CHOWDHURY, SB
    CHAKRABARTY, S
    CHAKRABARTY, T
    MUKHERJEE, DC
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1995, 103 (1-2) : 59 - 71
  • [9] Selective adsorption of chromium(VI) in industrial wastewater using low-cost abundantly available adsorbents
    Dakiky, M
    Khamis, M
    Manassra, A
    Mer'eb, M
    [J]. ADVANCES IN ENVIRONMENTAL RESEARCH, 2002, 6 (04): : 533 - 540
  • [10] El-Guendi MS., 1991, ADSORPT SCI TECHNOL, V8, P217, DOI DOI 10.1177/026361749100800404