Concomitant Reactivity of the m-Terphenylindium Dihydroxide [2,6-Mes2C6H3In(OH)2]4 toward Carbon Dioxide and Ethylene Glycol

被引：5
作者：
Ahmad, S. Usman [1 ]
Beckmann, Jens [1 ,2 ]
Duthie, Andrew [3 ]
机构：
[1] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany
[2] Univ Bremen, Inst Anorgan & Phys Chem, D-28358 Bremen, Germany
[3] Deakin Univ, Sch Life & Environm Sci, Waurn Ponds, Vic 3217, Australia
来源：
ORGANOMETALLICS | 2012年 / 31卷 / 09期
关键词：
DIMETHYL CARBONATE; METAL-COMPLEXES; SOLID-STATE; FIXATION; OXIDE; CATALYSTS; METHANOL; CO2; COPOLYMERIZATION; CHEMISTRY;
D O I：
10.1021/om3001857
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The stepwise reaction of [2,6-Mes(2)C(6)H(3)In(OH)(2)](4) with carbon dioxide and ethylene glycol proceeded with the formation of (2,6-Mes(2)C(6)H(3)In)(4)(CO3)(2)(OH)(4)(H2O)(2) (1) and (2,6-Mes(2)C(6)H(3)In)(4)(OCH2CH2O)(2)(OH)(4) (2), respectively, and eventually produced (2,6-Mes(2)C(6)H(3)In)(4)(CO3)(2)(OCH2CH2OH)(2)(OH)(2) (3). Attempts to liberate ethylene carbonate upon heating of 3 were unsuccessful.
引用
收藏
页码：3802 / 3805
页数：4
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