High Surface Area CeO2 Promoted Suzuki-Miyaura Cross-Coupling of Arylboronic Acids and Aryl Iodides

被引：6

作者：

Graziano Mayer, Marilyn ^{[1
]}

Nador, Fabiana ^{[1
]}

Alicia Volpe, Maria ^{[2
]}

Radivoy, Gabriel ^{[1
]}

机构：

[1] Univ Nacl Sur, Inst Quim Sur, INQUISUR CONICET UNS, Dept Quim, RA-8000 Bahia Blanca, Buenos Aires, Argentina

[2] PLAPIQUI CONICET UNS, RA-8000 Bahia Blanca, Buenos Aires, Argentina

来源：

SYNLETT | 2013年 / 24卷 / 03期

关键词：

biaryls; cross-coupling; cerium oxide; Suzuki-Miyaura reaction; palladium-free; PALLADIUM CATALYSTS; CARBON; CHLORIDES; EFFICIENT; WATER; CERIA; PD/C; LIGAND;

D O I：

10.1055/s-0032-1318111

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

High surface area cerium oxide (240 m(2)/g) efficiently promoted the Suzuki-Miyaura cross-coupling of aryl iodides with arylboronic acids, in the absence of palladium or any other transition-metal catalyst. Excellent selectivity towards the cross-coupling product was observed. Cerium oxide could be recovered and reused at least three times without any loss of activity.

引用

页码：338 / 342

页数：5

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