Determination of Bisphenols and Related Compounds in Honey and Their Migration from Selected Food Contact Materials

被引:59
作者
Cesen, Marjeta [1 ,2 ]
Lambropoulou, Dimitra [3 ]
Laimou-Geraniou, Maria [3 ]
Kosjek, Tina [1 ,2 ]
Blaznik, Urska [4 ]
Heath, David [1 ]
Heath, Ester [1 ,2 ]
机构
[1] Jozef Stefan Inst, Dept Environm Sci, Jamova Cesta 39, Ljubljana 1000, Slovenia
[2] Jozef Stefan Int Postgrad Sch, Jamova Cesta 39, Ljubljana 1000, Slovenia
[3] Aristotle Univ Thessaloniki, Dept Chem, Univ Campus, Thessaloniki 54124, Greece
[4] Natl Inst Publ Hlth, Trubarjeva Cesta 2, Ljubljana 1000, Slovenia
关键词
honey; bisphenol; analogue; BPA; BPAF; BPAP; BPB; BPC; BPE; BPF; BPS; BPZ; 4-cumylphenol; dihydroxybenzophenone; food contact material; migration; SOLID-PHASE EXTRACTION; POLYCARBONATE BABY; ANALOGS; BEVERAGES; LIQUID; BPA; CONTAMINANTS; RESIDUES; TOMATOES; BOTTLES;
D O I
10.1021/acs.jafc.6b03924
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
This study reports the analysis of nine bisphenols (BPA, BPAF, BPAP, BPB, BPC, BPE, BPF, BPS, and BPZ) and related compounds (4-cumylphenol and dihydroxybenzophenone) in honey and food simulant. After sample preconcentration with Oasis HLB cartridges, analytes were silylated and analyzed by GC-MS. The validated methods with LODs in sub ng g(-1) were applied to 36 honey samples from European and non-European countries and food simulant stored in selected corresponding containers. Honey samples contained BPA, BPAF, BPE, BPF, BPS, and BPZ in amounts up to 107, 53.5, 12.8, 31.6, 302, and 28.4 ng g(-1), respectively. Under simulating conditions, BPA and BPAF were detected in food simulant up to 42.2 and 19.8 ng mL(-1), respectively. In certain cases, the detected bisphenols in honey probably derive from a source other than the final packaging.
引用
收藏
页码:8866 / 8875
页数:10
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