Synthesis of Sulfated Zirconia by Grafting on Mesoporous SBA-15 by Sol-Gel Method

被引：0

作者：

Jin Dingfeng ^{[1
]}

Hu Guobo ^{[1
]}

Jin Hongxiao ^{[1
]}

Wang Xinqing ^{[1
]}

Hong Bo ^{[1
]}

Peng Xiaoling ^{[1
]}

Ge Hongliang ^{[1
]}

机构：

[1] China Jiliang Univ, Hangzhou 310018, Zhejiang, Peoples R China

来源：

RARE METAL MATERIALS AND ENGINEERING | 2012年 / 41卷

基金：

中国国家自然科学基金;

关键词：

sol-gel; mesoporous; sulfated zirconia; grafting;

D O I：

暂无

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Mesoporous SBA-15 silica graft sulfate zirconia materials via sol-gel method were investigated. SAXRD, XRD, N-2 adsorption-desorption and HRTEM were used to characterize the properties of this acid catalysts. SAXRD and XRD characterizations revealed that SO42-/ZrO2-SBA-15 catalysts with monolayer coverage can be obtained using this grafting technique. N-2 adsorption-desorption exhibits improved thermal stability. HRTEM presents that the ordered mesostructure of the mesoporous material is preserved at all calcination temperatures. The SO42-/ZrO2-SBA-15-500 catalyst showed the highest activity in the condensation between toluene and formaldehyde. The conversion of formaldehyde reached 35.7%.

引用

页码：379 / 382

页数：4

共 10 条

[1] A surface sol-gel process of TiO2 and other metal oxide films with molecular precision [J].

Ichinose, I ;

Senzu, H ;

Kunitake, T .

CHEMISTRY OF MATERIALS, 1997, 9 (06) :1296-&

[2]

Jin D F, 2008, J MAT ENG, V10, P6

[3] Synthesis of dimethyldiphenylmethane over supported 12-tungstophosphoric acid (H3PW12O40) [J].

Jin, DF ;

Hou, ZY ;

Luo, YM ;

Zheng, XM .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 243 (02) :233-238

[4] Microwave assisted in situ synthesis of USY-encapsulated heteropoly acid (HPW-USY) catalysts [J].

Jin, Dingfeng ;

Gao, Jing ;

Hou, Zhaoyin ;

Guo, Yan ;

Lu, Xiuyang ;

Zhu, Yinghong ;

Zheng, Xiaoming .

APPLIED CATALYSIS A-GENERAL, 2009, 352 (1-2) :259-264

[5]

Krishnan C K, 2008, ADV MATER, V9999, P1

[6] Water-tolerant solid acid catalysts [J].

Okuhara, T .

CHEMICAL REVIEWS, 2002, 102 (10) :3641-3665

[7]

Reddy JS, 1996, CATAL LETT, V38, P219

[8] Grafting sulfated zirconia on mesoporous silica [J].

Wang, Yong ;

Lee, Kwan-Young ;

Choi, Saemin ;

Liu, Jun ;

Wang, Li-Qiong ;

Peden, Charles H. F. .

GREEN CHEMISTRY, 2007, 9 (06) :540-544

[9] Surfactant-assisted synthesis of unprecedented hierarchical meso-macrostructured zirconia [J].

Yuan, ZY ;

Vantomme, A ;

Léonard, A ;

Su, BL .

CHEMICAL COMMUNICATIONS, 2003, (13) :1558-1559

[10] Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores [J].

Zhao, DY ;

Feng, JL ;

Huo, QS ;

Melosh, N ;

Fredrickson, GH ;

Chmelka, BF ;

Stucky, GD .

SCIENCE, 1998, 279 (5350) :548-552

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