A lab-on-a-molecule for anions in aqueous solution: using Kolbe electrolysis and radical methylation at iridium for sensing

被引：69

作者：

Schmittel, Michael ^{[1
]}

Shu Qinghai ^{[1
]}

机构：

[1] Univ Siegen, Ctr Micro & Nanochem & Engn, D-57068 Siegen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 21期

关键词：

ELECTROGENERATED CHEMILUMINESCENCE; ACETATE ION; CYANIDE; COMPLEXES; SENSOR; WATER; RECOGNITION; RECEPTORS; CHEMISTRY; BORANES;

D O I：

10.1039/c2cc17731e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iridium complex [(pq)(2)IrCl](2) (1) is established as a quantitatively operating lab-on-a-molecule in aqueous media at physiological pH. Acting as a chemodosimeter, 1 uses two channels, PL and ECL, for the detection of cyanide and acetate, with the former undergoing nucleophilic attack and the latter Kolbe electrolysis and radical-metal combination.

引用

页码：2707 / 2709

页数：3