Fabrication and properties of carbon nanotubes reinforced Fe/hydroxyapatite composites by in situ chemical vapor deposition

被引:32
作者
Li, Haipeng [1 ,2 ]
Zhao, Naiqin [1 ,3 ]
Liu, Yuan [1 ]
Liang, Chunyong [2 ]
Shi, Chunsheng [1 ]
Du, Xiwen [1 ]
Li, Jiajun [1 ]
机构
[1] Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China
[2] Hebei Univ Technol, Sch Mat Sci & Engn, Tianjin 300132, Peoples R China
[3] Tianjin Univ, Tianjin Key Lab Composite & Funct Mat, Tianjin 300072, Peoples R China
关键词
ceramic-matrix composites (CMCs); electron microscopy; chemical vapor deposition (CVD);
D O I
10.1016/j.compositesa.2008.04.007
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Carbon nanotubes (CNTs) (Fe)/hydroxyapatite (HA) composite powder with CNTs homogeneously dispersed was successfully prepared by a novel process, which involved producing Fe2O3/HA precursor, calcination in NZ atmosphere and reduction in hydrogen of the Fe2O3/HA precursor to yield Fe/HA catalyst, and in situ synthesis of nanotubes by chemical vapor deposition over Fe/HA catalyst. These excellent CNTs(Fe)/HA composite powder was then employed to produce CNTs(Fe)/HA bulk composites. The CNTs(Fe)/HA bulk nanocomposites produced by pressing and sintering of the CNTs(Fe)/HA composite powder presented that the CNTs distributed homogenously and bonded strongly with the HA matrix. The effective enhancement of mechanical properties of the composites was indicated by a 226% increase in fracture toughness and 49% increase in flexural strength compared to monolithic HA bulk. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1128 / 1132
页数:5
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