Influence of the materials magnetic state on the accurate determination of the magnetocaloric effect

被引:12
作者
Balli, M. [1 ]
Sari, O. [1 ,2 ]
Fruchart, D. [3 ]
Forchelet, J. [1 ]
机构
[1] Univ Appl Sci Western Switzerland, Inst Thermal Sci & Engn, CH-1401 Yverdon, Switzerland
[2] Clean Cool Syst Co, ADNV, CH-1400 Yverdon, Switzerland
[3] CNRS, Neel Inst, Dept MCMF, Grenoble, France
来源
EMM-FM2011 - FIRST EURO MEDITERRANEAN MEETING ON FUNCTIONALIZED MATERIALS | 2012年 / 29卷
关键词
ADIABATIC TEMPERATURE-CHANGE; ROOM-TEMPERATURE; ENTROPY CHANGE;
D O I
10.1051/epjconf/20122900005
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper, we report a detailed study of the magnetocaloric effect (MCE) in different first order magnetic transition (FOMT) materials with different situation of the magnetic state (magnetic order). For this purpose, R-Co-2, MnAs based compounds were considered in this study. The MCE is discussed in terms of Maxwell relation (MR) and Clausius-Clapeyron (C-C) equation. The deviation observed between both methods is discussed and analyzed. On the other hand, practically all the reported data of the MCE in the literature are associated to the applied external magnetic field and have not been corrected taking into account the demagnetization effect related to the materials shape. The obtained results demonstrate that this phenomenon can alter drastically the MCE values by cancelling out a large part of the external field, resulting in spurious values of the measured MCE. The effect of the demagnetization field on the magnetocaloric performances is also the subject of this paper.
引用
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页数:10
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共 25 条
[11]   Comment on "Direct measurement of the 'giant' adiabatic temperature change in Gd5Si2Ge2" -: Reply [J].
Földeàki, M ;
Chahine, R ;
Bose, TK ;
Barclay, JA .
PHYSICAL REVIEW LETTERS, 2000, 85 (19) :4192-4192
[12]   Itinerant-electron metamagnetic transition and large magnetocaloric effects in La(FexSi1-x)13 compounds and their hydrides -: art. no. 104416 [J].
Fujita, A ;
Fujieda, S ;
Hasegawa, Y ;
Fukamichi, K .
PHYSICAL REVIEW B, 2003, 67 (10)
[13]   Direct measurement of the "giant" adiabatic temperature change in Gd5Si2Ge2 [J].
Giguère, A ;
Foldeaki, M ;
Gopal, BR ;
Chahine, R ;
Bose, TK ;
Frydman, A ;
Barclay, JA .
PHYSICAL REVIEW LETTERS, 1999, 83 (11) :2262-2265
[14]   Comment on "Direct measurement of the 'giant' adiabatic temperature change in Gd5Si2Ge2" [J].
Gschneidner, KA ;
Pecharsky, VK ;
Brück, E ;
Duijn, HGM ;
Levin, EM .
PHYSICAL REVIEW LETTERS, 2000, 85 (19) :4190-4190
[15]   Very large magnetic entropy change near room temperature in LaFe11.2Co0.7Si1.1 [J].
Hu, FX ;
Shen, BG ;
Sun, JR ;
Wang, GJ ;
Cheng, ZH .
APPLIED PHYSICS LETTERS, 2002, 80 (05) :826-828
[16]   Adiabatic temperature change at first-order magnetic phase transitions:: Ni2.19Mn0.81Ga as a case study [J].
Khovaylo, V. V. ;
Skokov, K. P. ;
Koshkid'ko, Yu. S. ;
Koledov, V. V. ;
Shavrov, V. G. ;
Buchelnikov, V. D. ;
Taskaev, S. V. ;
Miki, H. ;
Takagi, T. ;
Vasiliev, A. N. .
PHYSICAL REVIEW B, 2008, 78 (06)
[17]   Determination of the entropy changes in the compounds with a first-order magnetic transition [J].
Liu, G. J. ;
Sun, J. R. ;
Shen, J. ;
Gao, B. ;
Zhang, H. W. ;
Hu, F. X. ;
Shen, B. G. .
APPLIED PHYSICS LETTERS, 2007, 90 (03)
[18]   The effect of partial substitution of In by Si on the phase transitions and respective magnetic entropy changes of Ni50Mn35In15 Heusler alloy [J].
Pathak, Arjun Kumar ;
Dubenko, Igor ;
Stadler, Shane ;
Ali, Naushad .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2008, 41 (20)
[19]   Making the most of the magnetic and lattice entropy changes [J].
Pecharsky, V. K. ;
Gschneidner, K. A., Jr. ;
Mudryk, Ya. ;
Paudyal, Durga .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2009, 321 (21) :3541-3547
[20]   Giant magnetocaloric effect in Gd-5(Si2Ge2) [J].
Pecharsky, VK ;
Gschneidner, KA .
PHYSICAL REVIEW LETTERS, 1997, 78 (23) :4494-4497