Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus

被引：59

作者：

Wild, Stefan ^{[1
,2
,3
]}

Fickert, Michael ^{[1
,2
,3
]}

Mitrovic, Aleksandra ^{[1
,2
,3
]}

Lloret, Vicent ^{[1
,2
,3
]}

Neiss, Christian ^{[4
,5
]}

Vidal-Moya, Jose Alejandro ^{[6
]}

Rivero-Crespo, Miguel Angel ^{[6
]}

Leyva-Perez, Antonio ^{[6
]}

Werbach, Katharina ^{[7
]}

Peterlik, Herwig ^{[7
]}

Grabau, Mathias ^{[8
]}

Wittkaemper, Haiko ^{[8
]}

Papp, Christian ^{[8
]}

Steinrueck, Hans-Peter ^{[8
]}

Pichler, Thomas ^{[7
]}

Goerling, Andreas ^{[4
,5
]}

Hauke, Frank ^{[1
,2
,3
]}

Abellan, Gonzalo ^{[1
,2
,3
,9
]}

Hirsch, Andreas ^{[1
,2
,3
]}

机构：

[1] Friedrich Alexander Univ Erlangen Nurnberg FAU, Chair Organ Chem 2, Nikolaus Fiebiger Str 10, D-91058 Erlangen, Germany

[2] Friedrich Alexander Univ Erlangen Nurnberg FAU, Joint Inst Adv Mat & Proc ZMP, Nikolaus Fiebiger Str 10, D-91058 Erlangen, Germany

[3] Dr Mack Str 81, D-90762 Furth, Germany

[4] Friedrich Alexander Univ Erlangen Nurnberg FAU, Lehrstuhl Theoret Chem, Egerlandstr 3, D-91058 Erlangen, Germany

[5] Friedrich Alexander Univ Erlangen Nurnberg FAU, ICMM, Egerlandstr 3, D-91058 Erlangen, Germany

[6] Univ Politecn Valencia, CSIC, Inst Tecnol & Quim, Avda Naranjos S-N, E-46022 Valencia, Spain

[7] Univ Vienna, Fac Phys, Strudlhofgasse 4, A-1090 Vienna, Austria

[8] FAU, Lehrstuhl Phys Chem 2, Egerlandstr 3, D-91058 Erlangen, Germany

[9] Univ Valencia, Inst Ciencia Mol ICMol, Catedrat Jose Beltran 2, Valencia 46980, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2019年 / 58卷 / 17期

基金：

欧洲研究理事会;

关键词：

P-31 NMR spectroscopy; black phosphorus; covalent functionalization; Raman spectroscopy; reductive route; PASSIVATION;

D O I：

10.1002/anie.201811181

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chemical bulk reductive covalent functionalization of thin-layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes.

引用

页码：5763 / 5768

页数：6

共 50 条

[41] Fabrication of an ideal nanoring from a black phosphorus nanoribbon upon movable bundling carbon nanotubes
Cai, Kun
Shi, Jiao
Liu, Lingnan
Qin, Qing H.
NANOTECHNOLOGY, 2017, 28 (38)
[42] The Art of Integrated Functionalization: Super Stable Black Phosphorus Achieved through Metal-Organic Framework Coating
Han, Bin
Duan, Zaihua
Xu, Jun
Zhu, Yuxiang
Xu, Qingchi
Wang, Hao
Tai, Huiling
Weng, Jian
Zhao, Yanli
ADVANCED FUNCTIONAL MATERIALS, 2020, 30 (27)
[43] Surface Functionalization of Black Phosphorus by Cu: Effective Electron Doping and Enhanced Photoresponse
Zheng, Yue
Yang, Hang
Han, Cheng
Mao, Hong Ying
ADVANCED MATERIALS INTERFACES, 2020, 7 (17)
[44] Post-Graphene 2D Chemistry: The Emerging Field of Molybdenum Disulfide and Black Phosphorus Functionalization
Hirsch, Andreas
Hauke, Frank
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (16) : 4338 - 4354
[45] Functionalization of small black phosphorus nanoparticles for targeted imaging and photothermal therapy of cancer
Lijuan Deng
Yifan Xu
Caixia Sun
Baofeng Yun
Qiao Sun
Chongjun Zhao
Zhen Li
ScienceBulletin, 2018, 63 (14) : 917 - 924
[46] Chemical Functionalization of 2D Black Phosphorus toward Its Applications in Energy Devices and Catalysis: A Review
Kuchkaev, Aidar M.
Lavate, Sneha
Kuchkaev, Airat M.
Sukhov, Aleksandr, V
Srivastava, Rohit
Yakhvarov, Dmitry G.
ENERGY TECHNOLOGY, 2021, 9 (12)
[47] Fullerene Covalent Passivation of Black Phosphorus Nanosheets toward Enhanced Near-Infrared-II Photothermal Therapy
Xie, Chang
Wang, Li
Liu, Yajuan
Chen, Muqing
Du, Pingwu
Wang, Yucai
Ma, Xiaopeng
Yang, Shangfeng
ACS APPLIED MATERIALS & INTERFACES, 2023, 15 (17) : 20686 - 20696
[48] Intrinsic Correlation between Electronic Structure and Degradation: From Few-Layer to Bulk Black Phosphorus
Kim, Minju
Kim, Han-gyu
Park, Soohyung
Kim, Jin Sung
Choi, Hyoung Joon
Im, Seongil
Lee, Hyunbok
Kim, Taekyeong
Yi, Yeonjin
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (12) : 3754 - 3758
[49] Lattice Anisotropy-Driven Reduction of Phonon Velocities in Black Phosphorus
Joshi, Prakriti Pradhan
Unruh, Davis
Mirzajani, Nasim
Gage, Thomas E.
Wang, Luqing
Li, Ruiyu
Liu, Haihua
Liang, Liangbo
Arslan, Ilke
Chan, Maria K. Y.
King, Sarah B.
ACS NANO, 2025, 19 (04) : 4324 - 4332
[50] Noncovalent Functionalization of 2D Black Phosphorus with Fluorescent Boronic Derivatives of Pyrene for Probing and Modulating the Interaction with Molecular Oxygen
Bolognesi, Margherita
Moschetto, Salvatore
Trapani, Mariachiara
Prescimone, Federico
Ferroni, Claudia
Manca, Gabriele
Ienco, Andrea
Borsacchi, Silvia
Caporali, Maria
Muccini, Michele
Peruzzini, Maurizio
Serrano-Ruiz, Manuel
Calucci, Lucia
Castriciano, Maria Angela
Toffanin, Stefano
ACS APPLIED MATERIALS & INTERFACES, 2019, 11 (25) : 22637 - 22647

← 1 2 3 4 5 →