Formation of multicomponent 2D assemblies of C2v-symmetric terphenyl tetracarboxylic acid at the solid/liquid interface: recognition, selection, and transformation

被引：15

作者：

Wang, Jie ^{[1
,2
]}

Wang, Li-Mei ^{[2
]}

Lu, Cheng ^{[2
]}

Yan, Hui-Juan ^{[2
]}

Wang, Shao-Xu ^{[1
]}

Wang, Dong ^{[2
]}

机构：

[1] Dalian Jiaotong Univ, Coll Environm & Chem Engn, Dalian 116028, Peoples R China

[2] Chinese Acad Sci, CAS Res & Educ Ctr Excellence Mol Sci, Inst Chem, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China

来源：

RSC ADVANCES | 2019年 / 9卷 / 21期

基金：

中国国家自然科学基金;

关键词：

LIQUID-SOLID INTERFACE; TRIMESIC ACID; POLYMORPHISM; MOLECULES; NETWORKS;

D O I：

10.1039/c9ra01493d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report on the two-dimensional self-assembly of C-2v-symmetric [1,1:3,1-terphenyl]-3,3,5,5-tetracarboxylic acid (TPTA) at the solid/liquid interface by using scanning tunneling microscopy (STM). Two kinds of different self-assembly structure, i.e. a close-packed and porous rosette structure, are formed by TPTA molecules through intermolecular hydrogen bonds. When adding coronene (COR) as a guest into the TPTA assembly, structural transformation from a densely packed row structure to a rosette network structure is observed. It was found that two kinds of cavities with different sizes in the rosette network structure can be used to realize the selective co-adsorption of guest molecules with appropriate shape and size. Three-component 2D host-guest structures were successfully constructed by using 1,2,3,4,5,6-hexakis(4-bromophenyl)benzene (HBPBE) and copper phthalocyanine (CuPc) as guest molecules.

引用

页码：11659 / 11663

页数：5

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