Casting of Gold Nanoparticles with High Aspect Ratios inside DNA Molds

被引:19
作者
Ye, Jingjing [1 ,2 ]
Weichelt, Richard [1 ,2 ,3 ,4 ]
Kemper, Ulrich [1 ,2 ]
Gupta, Vaibhav [5 ]
Koenig, Tobias A. F. [5 ]
Eychmueller, Alexander [3 ,4 ]
Seidel, Ralf [1 ,2 ]
机构
[1] Univ Leipzig, Mol Biophys Grp, Peter Debye Inst Soft Matter Phys, D-04103 Leipzig, Germany
[2] Tech Univ Dresden, Ctr Adv Elect Dresden, D-01062 Dresden, Germany
[3] Tech Univ Dresden, Phys Chem, D-01062 Dresden, Germany
[4] Tech Univ Dresden, Ctr Adv Elect Dresden, D-01062 Dresden, Germany
[5] Leibniz Inst Polymerforsch Dresden eV, Inst Phys Chem & Polymer Phys, Hohe Str 6, D-01069 Dresden, Germany
关键词
bottom-up; DNA origami; gold nanoparticles; metallization; nanoelectronics; ORIGAMI; NANOTECHNOLOGY;
D O I
10.1002/smll.202003662
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
DNA nanostructures provide a powerful platform for the programmable assembly of nanomaterials. Here this approach is extended to synthesize rod-like gold nanoparticles in a full DNA controlled manner. The approach is based on DNA molds containing elongated cavities. Gold is deposited inside the molds using a seeded-growth procedure. By carefully exploring the growth parameters it is shown that gold nanostructures with aspect ratios of up to 7 can be grown from single seeds. The highly anisotropic growth is in this case controlled only by the rather soft and porous DNA walls. The optimized seeded growth procedure provides a robust and simple routine to achieve continuous gold nanostructures using DNA templating.
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页数:6
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