Solid state structure of {[HC(3,5-Me2pz)3][HB(3,5-Me2pz)3]Cd}-{B[3,5-(CF3)2C6H3]4:: Comparison of the bonding of tris(pyrazolyl)methane and tris(pyrazolyl)borate ligands

被引：27

作者：

Reger, DL ^{[1
]}

Collins, JE

Rheingold, AL

Liable-Sands, LM

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 13期

关键词：

D O I：

10.1021/ic981453w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Cd-N bond distances for the tris(pyrazolyl)borate ligand in {[HC(3,5-Me(2)pz)(3)][HB(3,5-Me(2)pz)(3)]Cd}(+) average 0.09 Angstrom shorter than the Cd-N bond distances for the tris(pyrazolyl)methane ligand. In contrast, the average Cd-N distance in [HB(3,5-Me(2)pz)(3)](2)Cd (2.348(5) Angstrom) is very similar to that in {[HC(3,5-Me(2)pz)(3)](2)Cd}(2+) (2.321(10) Angstrom). Thus, the comparison of the bonding properties of the two ligands in the same complex is needed to differentiate bonding characteristics.

引用

页码：3235 / +

页数：4

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