Single-ion magnet behavior of a new mononuclear dysprosium complex

被引：36

作者：

Wang, Zhi-Gang ^{[1
,2
]}

Lu, Jing ^{[1
,2
]}

Gao, Chun-Yan ^{[1
,2
]}

Wang, Chao ^{[1
]}

Tian, Jin-Lei ^{[1
,2
]}

Gu, Wen ^{[1
]}

Liu, Xin ^{[1
]}

Yan, Shi-Ping ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

[2] Tianjin Key Lab Met & Mol Based Mat Chem, Tianjin 300071, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 27卷

基金：

中国国家自然科学基金;

关键词：

Dysprosium; Crystal structure; Magnetic property; Single-ion magnet; RELAXATION; DYNAMICS;

D O I：

10.1016/j.inoche.2012.10.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new mononuclear dysprosium complex formulated as [Dy(dppz) (tfnb)(3)]center dot 0.375H(2)O (dppz=dipyrido [3,2-a:2',3'-c]phenazine; tfnb= 4,4,4-trifluoro-1 -(2-naphthyl)-1,3- butanedione) was synthesized, structurally and magnetically characterized. X-ray diffraction study reveals that the central Dy-III ion in the complex adopts an approximately square-antiprismatic (SAP) geometry. The complex shows frequency-dependent ac magnetic susceptibilities, indicating single-ion magnet behavior. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：127 / 130

页数：4

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