Crystalline WS2 via Room Temperature, Solution-Phase Synthesis

被引：1

作者：

Zhang, He ^{[1
]}

Hock, Adam S. ^{[1
]}

机构：

[1] IIT, Dept Chem, 3101 South Dearborn St, Chicago, IL 60616 USA

来源：

INORGANIC CHEMISTRY | 2017年 / 56卷 / 01期

关键词：

ATOMIC LAYER DEPOSITION; HYDROGEN EVOLUTION; TUNGSTEN DISULFIDE; SINGLE-LAYER; OXIDE NANOPARTICLES; COLLOIDAL SYNTHESIS; VAPOR-DEPOSITION; MOS2; NANOSHEETS; PRECURSORS;

D O I：

10.1021/acs.inorgchem.6b02490

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystalline tungsten disulfide (WS2) has been prepared from the reaction of bis(cydopentadienyl) tungsten dihydride with sulfur at room temperature and ambient pressure in organic solvents. WS2 was characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, resonance Raman spectroscopy, transmission electron microscopy, and X-ray absorption spectroscopy, and the resulting WS2 is highly crystalline by X-ray diffraction. The low-temperature synthesis is hypothesized to be a result of highly mobile surface W Cp groups that are able to facilitate crystallization.

引用

页码：106 / 109

页数：4

共 50 条

[1] Solution-Phase Synthesis of Vanadium Intercalated 1T′-WS2 with Tunable Electronic Properties
Zhu, Kuixin
Tao, Yiyin
Clark, Daniel E.
Hong, Wei
Li, Christina W.
NANO LETTERS, 2023, 23 (10) : 4471 - 4478
[2] Solution-phase synthesis of monodispersed SnTe nanocrystallites at room temperature
An, CH
Tang, KB
Hai, B
Shen, GZ
Wang, CR
Qian, YT
INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (02) : 181 - 184
[3] Solution-Phase Activation and Functionalization of Colloidal WS2 Nanosheets with Ni Single Atoms
Meza, Erika
Diaz, Rosa E.
Li, Christina W.
ACS NANO, 2020, 14 (02) : 2238 - 2247
[4] Nucleation of WS2 fullerenes at room temperature
Margulis, L
Tenne, R
Iijima, S
MICROSCOPY MICROANALYSIS MICROSTRUCTURES, 1996, 7 (02): : 87 - 89
[5] Solution-Phase Synthesis of Crystalline Lithium Niobate Nanostructures
Wood, Bryan D.
Mocanu, Valentin
Gates, Byron D.
ADVANCED MATERIALS, 2008, 20 (23) : 4552 - 4556
[6] A room temperature solution-phase method to synthesize β-Ni(OH)2 nanoneedles
Wang, Wenzhong
Lu, Baoli
Wang, Yan
Zhang, Ning
Zhang, Guling
MATERIALS LETTERS, 2011, 65 (11) : 1591 - 1594
[7] Room temperature observation of biexcitons in exfoliated WS2 monolayers
Paradisanos, I.
Germanis, S.
Pelekanos, N. T.
Fotakis, C.
Kymakis, E.
Kioseoglou, G.
Stratakis, E.
APPLIED PHYSICS LETTERS, 2017, 110 (19)
[8] Solution-phase synthesis of nanomaterials at low temperature
Zhu YongChun
Qian Yitai
SCIENCE IN CHINA SERIES G-PHYSICS MECHANICS & ASTRONOMY, 2009, 52 (01): : 13 - 20
[9] Solution-phase synthesis of nanomaterials at low temperature
ZHU YongChun & QIAN YiTai Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry
Science China(Physics,Mechanics & Astronomy), 2009, (01) : 13 - 20
[10] Solution-phase synthesis of nanomaterials at low temperature
YongChun Zhu
YiTai Qian
Science in China Series G: Physics, Mechanics and Astronomy, 2009, 52 : 13 - 20

← 1 2 3 4 5 →