Bonding Mechanism Between Waterglass/Polyurethane Adhesive and Coal

被引:17
作者
Guan, Xue-mao [1 ]
Yang, Zheng-peng [1 ]
Zhang, Chun-jing [1 ]
机构
[1] Henan Polytech Univ, Inst Mat Sci & Engn, Jiaozuo 454000, Peoples R China
基金
高等学校博士学科点专项科研基金; 中国博士后科学基金;
关键词
Bonding; Coal; Mechanism; QCM; Waterglass/polyurethane adhesive; QUARTZ-CRYSTAL MICROBALANCE; COATINGS; PROTEIN; QCM;
D O I
10.1080/00218464.2012.694302
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Chemical grouting in underground coal mines is related closely to the interaction between grouting materials and coal. In the present work, a novel adhesive with high properties and low cost, waterglass/polyurethane, has been developed for coal bonding, based on a room-temperature-curing process. To obtain a direct and comprehensive understanding of the adhesive interaction at the surface of coal, quartz crystal microbalance (QCM) and Fourier-transform infrared spectroscopy (FTIR) techniques were employed to investigate the bonding process of waterglass/polyurethane adhesive on coal coating. The obtained information suggests that the interaction between the NCO groups in pMDI and the OH groups at the surface of coal is the dominant bonding force. The mechanical tests indicate that the compressive and flexural strength of the coal/adhesive composition can reach 21.4 and 5.8 MPa, respectively.
引用
收藏
页码:802 / 811
页数:10
相关论文
共 16 条
[11]   Detection of polycyclic aromatic hydrocarbons using quartz crystal microbalances [J].
Stanley, S ;
Percival, CJ ;
Auer, M ;
Braithwaite, A ;
Newton, MI ;
McHale, G ;
Hayes, W .
ANALYTICAL CHEMISTRY, 2003, 75 (07) :1573-1577
[12]  
STEWART JG, 1983, P 14 ANN I COAL MIN, P177
[13]   A QCM immunosensor for Salmonella detection with simultaneous measurements of resonant frequency and motional resistance [J].
Su, XL ;
Li, YB .
BIOSENSORS & BIOELECTRONICS, 2005, 21 (06) :840-848
[14]   Mechanism and kinetics of Pb(II) adsorption on ultrathin nanocrystalline titania coatings [J].
Yang, Zheng-peng ;
Zhang, Chun-jing .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 172 (2-3) :1082-1086
[15]   Mechanism and kinetics of apatite formation on nanocrystalline TiO2 coatings:: A quartz crystal microbalance study [J].
Yang, Zhengpeng ;
Si, Shihui ;
Zeng, Xiaoming ;
Zhang, Chunjing ;
Dai, Hongjuan .
ACTA BIOMATERIALIA, 2008, 4 (03) :560-568
[16]   Adsorption/desorption behavior of protein on nanosized hydroxyapatite coatings: A quartz crystal microbalance study [J].
Yang, Zhengpeng ;
Zhang, Chunjing .
APPLIED SURFACE SCIENCE, 2009, 255 (08) :4569-4574