Multifunctional zinc(II) urocanate with rare fivefold interpenetrating diamondoid network

被引:21
作者
Feng, Xia [1 ]
Wen, Yi-Hang [1 ]
Lan, You-Zhao [1 ]
Feng, Yun-Long [1 ]
Pan, Chun-Yu [1 ]
Yao, Yuan-Gen [2 ]
机构
[1] Zhejiang Normal Univ, Inst Phys Chem, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
关键词
Hydrothermal synthesis; Diamondiod network; 1D open channel; Non-linear optical effect; Photoluminescent property; Theory calculation; NONLINEAR-OPTICAL PROPERTIES; METAL-ORGANIC FRAMEWORK; CRYSTAL-STRUCTURE; COORDINATION POLYMERS; FLUORESCENT EMISSION; MAGNETIC-PROPERTY; NLO; COMPLEX;
D O I
10.1016/j.inoche.2008.11.017
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel zinc complex with rare 3D porous fivefold interpenetrating diamondoid network, {[Zn(L)(2)]H2O}(n)(HL = urocanic acid) (1), has been hydrothermally synthesized and characterized. It has notable non-linear optical (NLO) effect about three times as large as that of KDP and displays green fluorescent emission in the solid state. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:89 / 91
页数:3
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