The structure and properties of different types of starch exposed to UV radiation: A comparative study

被引：38

作者：

Bajer, Dagmara ^{[1
]}

Kaczmarek, Halina ^{[1
]}

Bajer, Krzysztof ^{[2
]}

机构：

[1] Nicolaus Copernicus Univ, Fac Chem, PL-87100 Torun, Poland

[2] Inst Engn Polymer Mat & Dyes, PL-87100 Torun, Poland

来源：

CARBOHYDRATE POLYMERS | 2013年 / 98卷 / 01期

关键词：

Starch properties; HPSEC; FTIR; X-ray diffraction; Photostability; AMYLOSE; CASSAVA;

D O I：

10.1016/j.carbpol.2013.05.090

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The effect of UV-irradiation on four different types of native starch (corn, waxy corn, wheat and potato) have been investigated. Although the changes in the chemical structure of starch specimens were small, indicating good photostability, the samples lost adsorbed water and their crystallinity degree decreased after irradiation. Moreover, a drop in average molecular weight occurred in samples (with the exception of potato starch) as a result of main chain scission. The variations in the properties of investigated specimens of various origin were related to the differences in their structure and macromolecular arrangement. The lowest photostability among the four starches was exhibited by potato starch. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：477 / 482

页数：6

共 23 条

[1] Biocomposites based on plasticized starch [J].

Averous, Luc ;

Halley, Peter J. .

BIOFUELS BIOPRODUCTS & BIOREFINING-BIOFPR, 2009, 3 (03) :329-343

[2] Structure development in amorphous starch as revealed by X-ray scattering: Influence of the network structure and water content [J].

Bayer, RK ;

Cagiao, ME ;

Calleja, FJB .

JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 99 (04) :1880-1886

[3] Evaluation of the phase composition of amylose by FTIR and isothermal immersion heats [J].

Bernazzani, P. ;

Peyyavula, V. K. ;

Agarwal, S. ;

Tatikonda, R. K. .

POLYMER, 2008, 49 (19) :4150-4158

[4] Photodegradation of cassava and corn starches [J].

Bertolini, AC ;

Mestres, C ;

Raffi, J ;

Buléon, A ;

Lerner, D ;

Colonna, P .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2001, 49 (02) :675-682

[5] Free radical formation in UV- and gamma-irradiated cassava starch [J].

Bertolini, AC ;

Mestres, C ;

Colonna, P ;

Raffi, J .

CARBOHYDRATE POLYMERS, 2001, 44 (03) :269-271

[6] Impact of Radiation Processing on Starch [J].

Bhat, Rajeev ;

Karim, A. A. .

COMPREHENSIVE REVIEWS IN FOOD SCIENCE AND FOOD SAFETY, 2009, 8 (02) :44-58

[7] Variation in crystalline type with amylose content in maize starch granules: an X-ray powder diffraction study [J].

Cheetham, NWH ;

Tao, LP .

CARBOHYDRATE POLYMERS, 1998, 36 (04) :277-284

[8] Effect of Drying Temperatures on Starch-Related Functional and Thermal Properties of Acorn Flours [J].

Correia, P. R. ;

Beirao-da-Costa, M. L. .

JOURNAL OF FOOD SCIENCE, 2011, 76 (02) :E196-E202

[9] Effect of acetylation and dual modification on physico-chemical, rheological and morphological characteristics of sweet potato (Ipomoea batatas) starch [J].

Das, Amit Baran ;

Singh, Gagandeep ;

Singh, Sukhcharan ;

Riar, Charanjit S. .

CARBOHYDRATE POLYMERS, 2010, 80 (03) :725-732

[10] Cryo-milling of starch granules leads to differential effects on molecular size and conformation [J].

Dhital, Sushil ;

Shrestha, Ashok K. ;

Flanagan, Bernadine M. ;

Hasjim, Jovin ;

Gidley, Michael J. .

CARBOHYDRATE POLYMERS, 2011, 84 (03) :1133-1140

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