A THEORETICAL ANALYSIS OF PHYSICAL PROPERTIES OF AQUEOUS TREHALOSE WITH BORAX

被引:0
作者
Sahara [1 ,2 ]
Aniya, Masaru [1 ]
机构
[1] Kumamoto Univ, Grad Sch Sci & Technol, Dept Phys, Kurokami 2-39-1, Kumamoto 8608555, Japan
[2] State Islamic Univ UIN Alauddin, Fac Sci & Technol, Dept Phys, Makassar, Indonesia
来源
Solid State Ionics: Ionics for Sustainable World | 2013年
关键词
GLASS-FORMING LIQUIDS; SODIUM-CHLORIDE; FRAGILITY; MODEL; TEMPERATURE; VISCOSITY; MIXTURES; EQUATION; POLYMERS;
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The temperature and composition dependence of the viscosity of aqueous trehalose and aqueous trehalose-borax mixtures has been investigated by means of the Bond Strength-Coordination Number Fluctuation (BSCNF) model. The result indicates that the variation in the fragility of the system is very small in the composition range analyzed. The values of the materials parameters determined are consistent with those of the trehalose-water-lithium iodide system which were analyzed in a previous study. Based on the analysis of the obtained parameters of the BSCNF model, the physical interpretation of the WLF parameters reported in a previous study is reconfirmed.
引用
收藏
页码:714 / 722
页数:9
相关论文
共 13 条
[1]   Why C-1=16-17 in the WLF equation is physical - and the fragility of polymers [J].
Angell, CA .
POLYMER, 1997, 38 (26) :6261-6266
[2]   A model for the fragility of the melts [J].
Aniya, M .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2002, 69 (03) :971-978
[3]   A model for the fragility of metallic glass forming liquids [J].
Aniya, Masaru ;
Shinkawa, Takaki .
MATERIALS TRANSACTIONS, 2007, 48 (07) :1793-1796
[4]   Bond strength-coordination number fluctuations and the fragility of some ion-conducting oxide and chalcogenide glass-forming liquids [J].
Aniya, Masaru ;
Ikeda, Masahiro .
IONICS, 2010, 16 (01) :7-11
[5]   Bond Strength-Coordination Number Fluctuation Model of Viscosity: An Alternative Model for the Vogel-Fulcher-Tammann Equation and an Application to Bulk Metallic Glass Forming Liquids [J].
Ikeda, Masahiro ;
Aniya, Masaru .
MATERIALS, 2010, 3 (12) :5246-5262
[6]   A thermodynamic connection to the fragility of glass-forming liquids [J].
Martinez, LM ;
Angell, CA .
NATURE, 2001, 410 (6829) :663-667
[7]   Viscosity and glass transition temperature of aqueous mixtures of trehalose with borax and sodium chloride [J].
Miller, DP ;
de Pablo, JJ ;
Corti, HR .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (46) :10243-10249
[8]   Electrical conductivity of supercooled aqueous mixtures of trehalose with sodium chloride [J].
Miller, DP ;
Conrad, PB ;
Fucito, S ;
Corti, HR ;
de Pablo, JJ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (44) :10419-10425
[9]   A comparative study of the viscosity of ion conducting polymers based on the bond strength-coordination number fluctuation model and other models [J].
Sahara ;
Aniya, Masaru .
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2012, 16 (05) :1883-1887
[10]  
Sahara, 2010, PHYS REP KUMAMOTO U, V13, P273