Detecting Hg2+ ions with an ICT fluorescent sensor molecule:: Remarkable emission spectra shift and unique selectivity

被引:346
作者
Wang, Jiaobing
Qian, Xuhong [1 ]
Cui, Jingnan
机构
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China
[2] E China Univ Sci & Technol, Sch Pharm, Shanghai Key Lab Chem Biol, Shanghai 200237, Peoples R China
关键词
D O I
10.1021/jo052642g
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A fluorescent ratiometric Hg2+ ion sensor RMS, based on a coumarin platform coupled with a tetraamide receptor, is presented. This sensor, employing the ICT mechanism, could be used to specifically detect Hg2+ ions in a neutral buffered water solution with an similar to 100-nm blue shift in emission spectra.
引用
收藏
页码:4308 / 4311
页数:4
相关论文
共 25 条
[21]   Environmental exposure to mercury and its toxicopathologic implications for public health [J].
Tchounwou, PB ;
Ayensu, WK ;
Ninashvili, N ;
Sutton, D .
ENVIRONMENTAL TOXICOLOGY, 2003, 18 (03) :149-175
[22]   Coumarins in polymers: From light harvesting to photo-cross-linkable tissue scaffolds [J].
Trenor, SR ;
Shultz, AR ;
Love, BJ ;
Long, TE .
CHEMICAL REVIEWS, 2004, 104 (06) :3059-3077
[23]  
Valeur B., 2001, MOL FLUORESCENCE PRI, P337
[24]   Two regioisomeric and exclusively selective Hg(II) sensor molecules composed of a naphthalimide fluorophore and an o-phenylenediamine derived triamide receptor [J].
Wang, JB ;
Qian, XH .
CHEMICAL COMMUNICATIONS, 2006, (01) :109-111
[25]   Fluorescent imaging of acute mercuric chloride exposure on cultured human kidney tubular epithelial cells [J].
Zhang, ZC ;
Guo, XF ;
Qian, XH ;
Lu, Z ;
Liu, FY .
KIDNEY INTERNATIONAL, 2004, 66 (06) :2279-2282