Detecting Hg2+ ions with an ICT fluorescent sensor molecule:: Remarkable emission spectra shift and unique selectivity

被引:346
作者
Wang, Jiaobing
Qian, Xuhong [1 ]
Cui, Jingnan
机构
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China
[2] E China Univ Sci & Technol, Sch Pharm, Shanghai Key Lab Chem Biol, Shanghai 200237, Peoples R China
关键词
D O I
10.1021/jo052642g
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A fluorescent ratiometric Hg2+ ion sensor RMS, based on a coumarin platform coupled with a tetraamide receptor, is presented. This sensor, employing the ICT mechanism, could be used to specifically detect Hg2+ ions in a neutral buffered water solution with an similar to 100-nm blue shift in emission spectra.
引用
收藏
页码:4308 / 4311
页数:4
相关论文
共 25 条
[1]   Bisheteroarylmethanes, part 9.: Metal chelation aptitudes of bis(o-azaheteroaryl)methanes as tuned by heterocycle charge demands [J].
Abbotto, A ;
Bradamante, S ;
Facchetti, A ;
Pagani, GA .
JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (16) :5753-5772
[2]   A highly selective fluorescent chemosensor for lead ions [J].
Chen, CT ;
Huang, WP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (22) :6246-6247
[3]  
Choi K, 2001, ANGEW CHEM INT EDIT, V40, P3912, DOI 10.1002/1521-3773(20011015)40:20<3912::AID-ANIE3912>3.0.CO
[4]  
2-R
[5]   Reversible colorimetric probes for mercury sensing [J].
Coronado, E ;
Galán-Mascaros, JR ;
Martí-Gastaldo, C ;
Palomares, E ;
Durrant, JR ;
Vilar, R ;
Gratzel, M ;
Nazeeruddin, MK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (35) :12351-12356
[6]   Intrazeolite photochemistry.: 22.: Acid-base properties of coumarin 6.: Characterization in solution, the solid state, and incorporated into supramolecular systems [J].
Corrent, S ;
Hahn, P ;
Pohlers, G ;
Connolly, TJ ;
Scaiano, JC ;
Fornes, V ;
García, H .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (30) :5852-5858
[7]   Signaling recognition events with fluorescent sensors and switches [J].
de Silva, AP ;
Gunaratne, HQN ;
Gunnlaugsson, T ;
Huxley, AJM ;
McCoy, CP ;
Rademacher, JT ;
Rice, TE .
CHEMICAL REVIEWS, 1997, 97 (05) :1515-1566
[8]   Coupling selectivity with sensitivity in an integrated chemosensor framework:: Design of a Hg2+-responsive probe, operating above 500 nm [J].
Descalzo, AB ;
Martínez-Máñez, R ;
Radeglia, R ;
Rurack, K ;
Soto, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (12) :3418-3419
[9]  
GRYNKIEWICZ G, 1985, J BIOL CHEM, V260, P3440
[10]   A highly selective and sensitive fluorescent chemosensor for Hg2+ in neutral buffer aqueous solution [J].
Guo, XF ;
Qian, XH ;
Jia, LH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (08) :2272-2273