Photochemical incorporation of N-benzylidene(phenyl)amine into the complex [{Ti(η5-C5Me5)(η-O)}3(μ3-CH)] as a model of the titanium oxide surface

被引：17

作者：

Gómez-Sal, P ^{[1
]}

Martín, A ^{[1
]}

Mena, M ^{[1
]}

Morales, MD ^{[1
]}

Santamaría, C ^{[1
]}

机构：

[1] Univ Alcala de Henares, Dept Quim Inorgan, E-28871 Madrid, Spain

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 18期

关键词：

D O I：

10.1039/a905129e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photochemical incorporation of PhCH=NPh to the metal oxide model [{TiCp*(mu-O)}(3)(mu(3)-CH)] (Cp* = eta(5)-C5Me5) occurs by breaking of the C=N imine bond and formation of mu-imido and sigma-alkenyl groups on the [Ti3O3] core; the crystal structure of the obtained product, [{TiCp*(mu-O)}(3)(mu-NPh)(CH=CHPh)], was determined by X-ray diffraction.

引用

页码：1839 / 1840

页数：2

共 24 条

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