(K0.5Na0.5)NbO3-Bi(Mg0.5Ti0.5)O3 solid solution: phase evolution, microstructure and electrical properties

被引:13
作者
He, Fen [1 ]
Chen, Xiuli [1 ]
Chen, Jie [1 ]
Wang, Yiliang [1 ]
Zhou, Huanfu [1 ]
Fang, Liang [1 ]
机构
[1] Guilin Univ Technol, Coll Mat Sci & Engn, Key Lab New Proc Technol Nonferrous Met & Mat, Guangxi Sci Expt Ctr Min Met & Environm,Minist Ed, Guilin 541004, Peoples R China
关键词
FREE PIEZOELECTRIC CERAMICS; LEAD-FREE CERAMICS; SINTERING TEMPERATURE; DIELECTRIC-PROPERTIES; DEPENDENCE;
D O I
10.1007/s10854-013-1409-6
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Lead-free piezoelectric ceramics with the composition of (1 - x)(K0.5Na0.5)NbO3-xBi(Mg0.5Ti0.5)O-3 [(1 - x)KNN-xBMT, 0 a parts per thousand currency sign x a parts per thousand currency sign 0.04] were synthesized via solid-state reaction method. X-ray diffraction patterns revealed that the orthorhombic-tetragonal phase transition was present for (1 - x)KNN-xBMT with increasing the content of BMT. The study of dielectric properties illustrated that both peaks of orthorhombic-tetragonal (T (O-T) ) and tetragonal-cubic (T (T-C) ) phase transitions shifted to lower temperature. Through adding BMT, the electrical properties of KNN ceramics were obviously improved. The optimized piezoelectric and ferroelectric properties with d (33) = 127 pC/N, k (p) = 36.58 %, P (r) = 22.1 mu C/cm(2) were obtained as x = 0.01.
引用
收藏
页码:4346 / 4350
页数:5
相关论文
共 45 条
[1]  
[Anonymous], 2012, ADV MAT LETT
[2]   High Temperature Piezoelectric Ceramics Based on xPbTiO3-(1-x)Bi(Sc1/2Me1/4Ti1/4)O3(Me = Zn, Mg) Ternary Perovskites [J].
Ansell, Troy Y. ;
Nikkel, Jason ;
Cann, David P. ;
Sehirlioglu, Alp .
JAPANESE JOURNAL OF APPLIED PHYSICS, 2012, 51 (10)
[3]   Neutron powder diffraction study on the crystal and magnetic structures of BiCoO3 [J].
Belik, AA ;
Iikubo, S ;
Kodama, K ;
Igawa, N ;
Shamoto, S ;
Niitaka, S ;
Azuma, M ;
Shimakawa, Y ;
Takano, M ;
Izumi, F ;
Takayama-Muromachi, E .
CHEMISTRY OF MATERIALS, 2006, 18 (03) :798-803
[4]   PHASE TRANSITIONS IN SYSTEM BATIO3-KNBO3 [J].
BRATTON, RJ ;
TIEN, TY .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1967, 50 (02) :90-&
[5]   The effects of sintering temperature on the properties of (Na0.5K0.5)NbO3-CaTiO3 based lead-free ceramics [J].
Chang, Ren-Chuan ;
Chu, Sheng-Yuan ;
Lin, Yi-Fang ;
Hong, Cheng-Shong ;
Kao, Po-Ching ;
Lu, Chun-Hsien .
SENSORS AND ACTUATORS A-PHYSICAL, 2007, 138 (02) :355-360
[6]   Properties of (Na0.5K0.5)NbO3-SrTiO3 based lead-free ceramics and surface acoustic wave devices [J].
Chang, Ren-Chuan ;
Chu, Sheng-Yuan ;
Wong, Yi-Peng ;
Lin, Yi-Fang ;
Hong, Cheng-Shong .
SENSORS AND ACTUATORS A-PHYSICAL, 2007, 136 (01) :267-272
[7]  
Chang Y.F., 2007, J APPL PHYS, V104
[8]   Effects of AETiO3 additions on phase structure, microstructure and electrical properties of (K0.5Na0.5)NbO3 ceramics [J].
Chang, Yunfei ;
Yang, Zupei ;
Wei, Lingling ;
Liu, Bing .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2006, 437 (02) :301-305
[9]   Effects of sintering temperature on the dielectric and piezoelectric properties of Sr additive Sm-modified PbTiO3 ceramics [J].
Chen, TY ;
Chu, SY ;
Juang, YD .
SENSORS AND ACTUATORS A-PHYSICAL, 2002, 102 (1-2) :6-10
[10]   Dielectric properties of (Ba0.8Sr0.2)(ZrxTi1-x)O3 thin films grown by pulsed-laser deposition [J].
Cheng, BL ;
Wang, C ;
Wang, SY ;
Lu, HB ;
Zhou, YL ;
Chen, ZH ;
Yang, GZ .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2005, 25 (12) :2295-2298