SNH Arylation of 1,3,7-triazapyrenes in acidic aqueous solution

被引：9
作者：
Borovlev, I. V. [1 ]
Demidov, O. P. [1 ]
Saigakova, N. A. [1 ]
机构：
[1] North Caucasus Fed Univ, Stavropol 355009, Russia
来源：
CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2013年 / 49卷 / 04期
关键词：
1,3,7-triazapyrenes; hetarylation; nucleophilic substitution of hydrogen; NUCLEOPHILIC-SUBSTITUTION; HYDROXYLATION; HYDROGEN;
D O I：
10.1007/s10593-013-1289-y
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of 1,3,7-triazapyrenes with pi-electron rich arenes in concentrated hydrochloric acid yielded the corresponding 6-aryl-1,3,7-triazapyrenes. An example of double arylation of 1,3,7-triaza-pyrene was found.
引用
收藏
页码：618 / 623
页数：6
相关论文
共 14 条
  • [1] A new method for [c,d]pyridine peri-annelation:: synthesis of azapyrenes from phenalenes and their dihydro derivatives
    Aksenov, Alexander V.
    Borovlev, Ivan V.
    Aksenova, Inna V.
    Pisarenko, Sergey V.
    Kovalev, Draitry A.
    [J]. TETRAHEDRON LETTERS, 2008, 49 (04) : 707 - 709
  • [2] 1,3-Dipolar Cycloaddition in a Series of 7-Oxoalkyl-1,3,7-Triazapyrenium salts
    Borovlev, I. V.
    Demidov, O. P.
    Pisarenko, S. V.
    Nemykina, O. A.
    Saigakova, N. A.
    [J]. CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2012, 48 (07) : 1064 - 1070
  • [3] Borovlev I. V., 2009, ZH ORG KHIM, V45, P1739
  • [4] An Oxidative Alkylamination of 1,3,7-Triazapyrenes in the Aqueous Medium
    Borovlev, Ivan
    Demidov, Oleg
    Saigakova, Nadezhda
    Pisarenko, Sergey
    Nemykina, Olesya
    [J]. JOURNAL OF HETEROCYCLIC CHEMISTRY, 2011, 48 (05) : 1206 - 1210
  • [5] Reactivity of the acridine ring: A review
    Chiron, J
    Galy, JP
    [J]. SYNTHESIS-STUTTGART, 2004, (03): : 313 - 325
  • [6] NUCLEOPHILIC-SUBSTITUTION OF HYDROGEN IN AZINES
    CHUPAKHIN, ON
    CHARUSHIN, VN
    VANDERPLAS, HC
    [J]. TETRAHEDRON, 1988, 44 (01) : 1 - 34
  • [7] OXIDATIVE AMINATION AND HYDROXYLATION OF 1,3,7-TRIAZAPYRENES IN AQUEOUS MEDIUM
    Demidov, O. P.
    Borovlev, I. V.
    Saigakova, N. A.
    Nemykina, O. A.
    Demidova, N. V.
    Pisarenko, S. V.
    [J]. CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2011, 47 (01) : 114 - 116
  • [8] OXIDATIVE SNH-ALKOXYLATION OF 1,3,7-TRIAZAPYRENES
    Demidov, O. P.
    Borovlev, I. V.
    Pisarenko, S. V.
    Nemykina, O. A.
    Saigakova, N. A.
    [J]. CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2010, 46 (05) : 636 - 638
  • [9] Demidov O. P., 2010, ZH OBSHCH KHIM, V80, P165
  • [10] Nucleophilic substitution of hydrogen in heterocyclic chemistry
    Makosza, M
    Wojciechowski, K
    [J]. CHEMICAL REVIEWS, 2004, 104 (05) : 2631 - 2666
12