Leaching indices of some major triazine metabolites

被引:49
作者
Bottoni, P
Keizer, J
Funari, E
机构
[1] Laboratorio di Igiene Ambientale, Istituto Superiore di Sanità, 00161 Rome, Viale Regina Elena
关键词
triazines; metabolites; DT50; Koc; leaching potential; GUS indices;
D O I
10.1016/0045-6535(96)00049-5
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Pesticide metabolites which maintain the phytotoxic activity of the parent compounds or some kind of biological activity may represent a risk to human health if present in drinking water above certain concentrations. Using laboratory methods, the soil persistence (DT50) and mobility (Koc) of desethylatrazine, deisopropylatrazine, desethylterbuthylazine, 3-(4- hydroxycyclohexyl)-6-(methylamino)-1-methyl-1,3,5-triazine-2,4-(1H,3H)-dione and of their parent compounds atrazine, terbutylazine, hexazinone were determined. Then, their tendency to leach (GUS indices) were calculated. Respect to their parent compounds, the examined metabolites generally have higher DT50 and lower Koc values. Consequently, they show leaching characteristics higher than their parent compounds. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:1401 / 1411
页数:11
相关论文
共 22 条
[1]   THE INFLUENCE OF SOIL PROPERTIES ON THE RATES OF DEGRADATION OF METAMITRON, METAZACHLOR AND METRIBUZIN [J].
ALLEN, R ;
WALKER, A .
PESTICIDE SCIENCE, 1987, 18 (02) :95-111
[2]  
[Anonymous], 1993, GUIDELINES DRINKING, V1
[3]  
Conway RA, 1982, ENV RISK ANAL CHEM, P198
[4]   K-OC ESTIMATION OF DEETHYLATRAZINE, DEISOPROPYLATRAZINE, HEXAZINONE AND TERBUTHYLAZINE BY REVERSED-PHASE CHROMATOGRAPHY AND SORPTION ISOTHERMS [J].
DONATI, L ;
KEIZER, J ;
BOTTONI, P ;
SCENATI, R ;
FUNARI, E .
TOXICOLOGICAL AND ENVIRONMENTAL CHEMISTRY, 1994, 44 (1-2) :1-10
[5]   DISSIPATION OF ATRAZINE RESIDUES FROM SOILS [J].
FRANK, R ;
SIRONS, GJ .
BULLETIN OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY, 1985, 34 (04) :541-548
[6]  
Funari Enzo, 1995, P3
[7]  
GUSTAFSON DI, 1989, ENVIRON TOXICOL CHEM, V8, P339, DOI 10.1897/1552-8618(1989)8[339:GUSASM]2.0.CO
[8]  
2
[9]   EFFECT OF PH ON THE DEGRADATION OF ATRAZINE, DICHLORPROP, LINURON AND PROPYZAMIDE IN SOIL [J].
HANCE, RJ .
PESTICIDE SCIENCE, 1979, 10 (01) :83-86
[10]   THE ESTIMATION OF THE ADSORPTION COEFFICIENT (KOC) FOR SOILS BY HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY [J].
HODSON, J ;
WILLIAMS, NA .
CHEMOSPHERE, 1988, 17 (01) :67-77