Polyhedral oligosilsesquioxane tethered perylene diimide for application in optical limiting and rapid detection of fluoride ions

被引：30

作者：

Gao, Tian ^{[1
]}

Zhou, Wen-Fa ^{[2
]}

Zhao, Yang ^{[1
]}

Shen, Lei ^{[2
]}

Chang, Wen-Ying ^{[3
]}

Musendo, Rodney-Kudzai ^{[1
]}

Chen, Er-Qiang ^{[3
]}

Song, Ying-Lin ^{[2
]}

Ren, Xiang-Kui ^{[1
]}

机构：

[1] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300350, Peoples R China

[2] Soochow Univ, Sch Phys Sci & Technol, Suzhou 215006, Peoples R China

[3] Peking Univ, Coll Chem, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 20期

基金：

中国国家自然科学基金;

关键词：

CRYSTAL-STRUCTURE; SHAPE-PERSISTENT; TRANSISTORS;

D O I：

10.1039/c8cc09725a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel perylene diimide derivative equipped with polyhedral oligosilsesquioxane nanocages (POSS-AMPDI) was designed and synthesized for application in optical limiting. Moreover, due to the dual mechanisms of POSS collapse and intermolecular proton transfer, POSS-AMPDI exhibits high sensitivity and rapid selectivity to fluoride ions, with a detection limit as low as 1.64 x 10(-8) M.

引用

页码：3012 / 3014

页数：3

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