Enhancement of proton exchange membrane fuel cell performance by doping microporous layers of gas diffusion layers with multiwall carbon nanotubes

被引:61
作者
Schweiss, Ruediger [1 ]
Steeb, Marcus [1 ]
Wilde, Peter M. [1 ]
Schubert, Tim [2 ]
机构
[1] SGL Carbon GmbH, D-86405 Meitingen, Germany
[2] FutureCarbon GmbH, D-95448 Bayreuth, Germany
关键词
Carbon nanotubes; Gas diffusion layer; PEM fuel cell; Microporous layers; MASS-TRANSPORT; CATHODE GDL; ELECTRODES; WATER; MANAGEMENT; POROSITY;
D O I
10.1016/j.jpowsour.2012.07.078
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Microporous layers (MPLs) of gas diffusion layers (GDLs) were modified by multiwall carbon nanotubes (MWCNTs) using a wet-chemical approach. Carbon nanotubes were dispersed along with other MPL components and coated onto a GDL backing. The electronic resistance of the GDL was significantly reduced by the addition of MWCNTs. A larger mean pore diameter was obtained as compared to the reference substrates. The improved performance of proton exchange membrane fuel cells (PEMFCs) using such CNT-doped GDLs is attributed to a lower electronic resistance along with improved mass transport. Synergy effects of different carbon materials with MWCNTs and advanced dispersion processes were found to play a key role in achieving the performance improvements. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:79 / 83
页数:5
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