Design, Synthesis, and Self-Assembly of Janus Bottlebrush Polymers

被引：39
|
作者：
Chen, Kerui [1 ,2 ]
Hu, Xin [2 ,3 ]
Zhu, Ning [1 ,2 ]
Guo, Kai [1 ,2 ]
机构：
[1] Nanjing Tech Univ, Coll Biotechnol & Pharmaceut Engn, 30 S Puzhu Rd, Nanjing 211800, Jiangsu, Peoples R China
[2] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, 30 S Puzhu Rd, Nanjing 211800, Jiangsu, Peoples R China
[3] Nanjing Tech Univ, Coll Mat Sci & Engn, 30 S Puzhu Rd, Nanjing 211800, Jiangsu, Peoples R China
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2020年 / 41卷 / 20期
基金：
国家重点研发计划;
关键词：
bottlebrush polymers; Janus; ring-opening metathesis polymerization; self-assembly; OPENING METATHESIS POLYMERIZATION; LIVING ANIONIC-POLYMERIZATION; END-NORBORNYL POLYSTYRENE; BLOCK-COPOLYMERS; BRUSH COPOLYMERS; GRAFTING DENSITY; MACROMOLECULAR BRUSHES; MOLECULAR BRUSHES; FACILE SYNTHESIS; SIDE-CHAINS;
D O I：
10.1002/marc.202000357
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Janus bottlebrush polymers are a class of special molecular brushes, which have two immiscible side chains on the repeating unit of the backbone. The characteristic architectures of Janus bottlebrush polymers enable unique self-assembly properties and broad applications. Recently, remarkable advances of Janus bottlebrush polymers have been achieved for polymer chemistry and material science. This review summarizes the synthetic strategies of Janus bottlebrush polymers, and highlights the self-assembly applications. Finally, the challenges and opportunities are proposed for the further development.
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页数：16
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