Catalytic cracking of n-hexane over MeAPOs molecular sieves

被引：0

作者：

Feng, Lili ^{[1
]}

Wang, Chongchen ^{[1
]}

Qi, Xingyi ^{[2
]}

机构：

[1] Beijing Univ Civil Engn & Architecture, Minist Educ, Key Lab Urban Stormwater Syst & Water Environm, Beijing 100044, Peoples R China

[2] Beihang Univ, Sch Chem & Environ, Beijing 100191, Peoples R China

来源：

APPLICATION OF CHEMICAL ENGINEERING, PTS 1-3 | 2011年 / 236-238卷

关键词：

MeAPO-5; MeAPO-11; n-Hexane; Catalytic cracking; ZEOLITES;

D O I：

10.4028/www.scientific.net/AMR.236-238.1063

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Mg-, Zn-, and Cu-substituted aluminophosphate molecular sieves (MeAPO-5 and MeAPO-11) were synthesized by hydrothermal crystallization method. The n-hexane cracking performance over the as-prepared MeAPOs was estimated under different reaction conditions. MeAPO-5 molecular sieves exhibited higher activity for the cracking conversion in the temperature range of 723 similar to 823 K than MeAPO-11. The conversion level of n-hexane over MeAPOs with the same topology had the following order: MgAPOs > ZnAPOs > CuAPOs. The cracking results showed that the conversion level of n-hexane increased with increasing reaction temperatures and contact time, and that the first order is determined in the n-hexane concentration.

引用

页码：1063 / +

页数：2

共 10 条

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