First enantioselective catalysis using a helical diphosphane

被引：200
作者：
Reetz, MT
Beuttenmuller, EW
Goddard, R
机构：
[1] Max-Planck-Inst. fur Kohlenforschung, D-45470 Mülheim/Ruhr
来源：
TETRAHEDRON LETTERS | 1997年 / 38卷 / 18期
关键词：
D O I：
10.1016/S0040-4039(97)00562-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis of 2,15-bis(diphenylphosphino)-hexahelicene (PHelix) in enantiomerically pure form and its use as a helical ligand for enantioselective rhodium-catalyzed hydrogenation are described. (C) 1997 Elsevier Science Ltd.
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页码：3211 / 3214
页数：4
相关论文
共 10 条
  • [1] BEUTTENMULLER EW, 1997, THESIS U BOCHUM
  • [2] Brunner H., 1993, HDB ENANTIOSELECTIVE
  • [3] LAARHOVEN WH, 1984, TOP CURR CHEM, V125, P63
  • [4] Noyori R., 1994, ASYMMETRIC CATALYSIS
  • [5] CHIRAL SEMICORRINS AND RELATED NITROGEN-HETEROCYCLES AS LIGANDS IN ASYMMETRIC CATALYSIS
    PFALTZ, A
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (06) : 339 - 345
  • [6] Rango C. De, 1973, CRYST STRUCT COMMUN, V2, P189
  • [7] SHELDRICK G, 1993, SHELXL 93
  • [8] PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES
    SHELDRICK, GM
    [J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 : 467 - 473
  • [9] Terfort A, 1997, SYNTHESIS-STUTTGART, P79
  • [10] SYNTHESIS AND CHIRAL RECOGNITION OF OPTICALLY-ACTIVE CROWN ETHERS INCORPORATING A HELICENE MOIETY AS THE CHIRAL CENTER
    YAMAMOTO, K
    IKEDA, T
    KITSUKI, T
    OKAMOTO, Y
    CHIKAMATSU, H
    NAKAZAKI, M
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1990, (02): : 271 - 276
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