Synthesis and characterization of chiral catenanes based on rigid calix[4]arene

被引:8
|
作者
Okada, Y [1 ]
Miao, ZH
Akiba, M
Nishimura, J
机构
[1] Gunma Univ, Dept Chem, Kiryu, Gumma 3768515, Japan
[2] Gunma Univ, Dept Nanomat Syst, Kiryu, Gumma 3768515, Japan
关键词
calixarene; catenane; enantiomer; circular dichroism;
D O I
10.1016/j.tetlet.2006.02.083
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new class of chiral calix[4]arene-based [2]catenanes was synthesized in excellent yields of 51-80%. They exhibit unique dynamic properties according to variable temperature NMR experiments. The enantiomeric pure (+)-catenane was prepared in 66% yield starting from (-)-calix[4]arene. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2699 / 2702
页数:4
相关论文
共 50 条
  • [1] Calix[4]arene-based bis[2]catenanes:: Synthesis and chiral resolution
    Molokanova, Olena
    Bogdan, Anca
    Vysotsky, Myroslav O.
    Bolte, Michael
    Ikai, Tomoyuki
    Okamoto, Yoshio
    Boehmer, Volker
    CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (21) : 6157 - 6170
  • [2] Calix[4]arene-Based Bis[2]catenanes: synthesis and chiral resolution
    Fachbereich Chemie, Pharmazie und Geowissenschaften, Abteilung Lehramt Chemie, Johannes Gutenberg-Universität Mainz, Duesbergweg 10-14, 55099 Mainz, Germany
    不详
    不详
    Chem. Eur. J., 21 (6157-6170):
  • [3] Synthesis of new rigid dimeric calix[4]arene
    Taghvaei-Ganjali, S.
    Zadmard, R.
    SUPRAMOLECULAR CHEMISTRY, 2008, 20 (05) : 527 - 530
  • [4] Chiral Recognition Based on Calix[4]arene
    Qing Guangyan
    Liu Shunying
    He Yongbing
    PROGRESS IN CHEMISTRY, 2008, 20 (12) : 1933 - 1944
  • [5] CHIRAL CALIX[4]ARENE
    SHINKAI, S
    ARIMURA, T
    KAWABATA, H
    MURAKAMI, H
    IWAMOTO, K
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1991, (10): : 2429 - 2434
  • [6] The synthesis and characterization of calix[4]arene based azo dyes
    Menon, Shobhana K.
    Patel, Ravindra V.
    Panchal, Jayesh G.
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2010, 67 (1-2) : 73 - 79
  • [7] The synthesis and characterization of calix[4]arene based azo dyes
    Shobhana K. Menon
    Ravindra V. Patel
    Jayesh G. Panchal
    Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2010, 67 : 73 - 79
  • [8] Anion-templated calix[4]arene-based pseudorotaxanes and catenanes
    Lankshear, Michael D.
    Evans, Nicholas H.
    Bayly, Sinion R.
    Beer, Paul D.
    CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (14) : 3861 - 3870
  • [9] Synthesis and Chiral Recognition of a New Type of Chiral Calix[4]arene Derivatives
    何永炳
    李剑峰
    肖元晶
    隗兰华
    吴晓军
    孟令芝
    Chinese Journal of Chemistry, 2003, (01) : 83 - 86
  • [10] INHERENTLY CHIRAL CALIX[4]ARENE
    NO, K
    KIM, JE
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1995, 16 (11) : 1122 - 1125