Open-air oxidative Heck reactions at room temperature

被引：70

作者：

Enquist, PA ^{[1
]}

Lindh, J ^{[1
]}

Nilsson, P ^{[1
]}

Larhed, M ^{[1
]}

机构：

[1] BMC, Dept Med Chem, Uppsala, Sweden

来源：

GREEN CHEMISTRY | 2006年 / 8卷 / 04期

关键词：

D O I：

10.1039/b517152k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium(II)-catalyzed oxidative Heck arylation reactions proceed at room temperature with atmospheric air as the sole reoxidant. Using arylboronic acids as arylating agents and inexpensive 2,9-dimethyl-1,10-phenanthroline as the supporting ligand, efficient vinylic substitution reactions were obtained both with electron-poor and electron-rich olefins on a 1 - 50 mmol scale.

引用

页码：338 / 343

页数：6

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