Synthesis, crystal structures, and fluorescence properties of two 1-D zinc(II) coordination polymers constructed from a bis(benzimidazole) ligand

被引：18

作者：

Xiao, Shu Lin ^{[1
]}

Zhao, Yan Qin ^{[1
]}

He, Cui Hong ^{[1
]}

Cui, Guang Hua ^{[1
]}

机构：

[1] Hebei United Univ, Coll Chem Engn, Tangshan, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 66卷 / 01期

关键词：

Bis(benzimidazole); Crystal structure; Fluorescence properties; Zinc(II) coordination polymers; FLEXIBLE BIS(BENZIMIDAZOLE); CATALYTIC-PROPERTIES; BUILDING-BLOCKS; COMPLEXES; METAL; CADMIUM(II); METALLACYCLES; DERIVATIVES; COPPER(II); DIVERSITY;

D O I：

10.1080/00958972.2012.748190

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Zn(L)(HCOO)Cl]n (1) and {[Zn2(L)2(OH)(HCOO)Cl]center dot I}n (2) have been obtained by hydrothermal methods of zinc chloride with 1,3-bis(5,6-dimethylbenzimidazole-1-ylmethyl)benzene (L) and potassium bromide (or potassium iodide), and are characterized by elemental analysis, IR spectra, X-ray powder diffraction, and single-crystal X-ray diffraction. The zinc(II) centers display tetrahedral coordination in 1 and 2. Solid 1 forms a one-dimensional (1-D) helical chain bridged by L, which is further arranged into a two-dimensional supramolecular structure through intermolecular pp stacking interactions. A 1-D ladder-like chain of 2 connected by hydroxyl and L is presented. Solid-state fluorescent properties of 1 and 2 have been investigated.

引用

页码：89 / 97

页数：9

共 48 条

[21] Formation of [FeW12O40]5- under hydrothermal conditions: syntheses, crystal structures, and characterization of [Fe(2,2′-bipy)3]2[HFeW12O40]•5H2O and (4,4′-H2bipy)6(Hpy)2(H3O)[FeW12O40]3•11H2O [J].

Li, Jia ;

Chen, Ya-Guang ;

Zhang, Chun-Jing .

JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (23) :3810-3818

[22] Assembly of [CunIn]-based coordination polymers from cracking the 3D framework of bulk CuI via flexible N-heterocyclic ligands [J].

Li, Ling-Ling ;

Li, Hong-Xi ;

Ren, Zhi-Gang ;

Liu, Dong ;

Chen, Yang ;

Zhang, Yong ;

Lang, Jian-Ping .

DALTON TRANSACTIONS, 2009, (40) :8567-8573

[23] Varying Ligand Backbones for Modulating the Interpenetration of Coordination Polymers Based on Homoleptic Cobalt(II) Nodes [J].

Li, Zuo-Xi ;

Xu, Yao ;

Zuo, Yi ;

Li, Lei ;

Pan, Qinhe ;

Hu, Tong-Liang ;

Bu, Xian-He .

CRYSTAL GROWTH & DESIGN, 2009, 9 (09) :3904-3909

[24] INFLUENCE OF 5,6-DIMETHYLBENZIMIDAZOLE (DMB) ON VITAMIN-B12 BIOSYNTHESIS BY STRAINS OF PROPIONIBACTERIUM [J].

MARWAHA, SS ;

SETHI, RP ;

KENNEDY, JF .

ENZYME AND MICROBIAL TECHNOLOGY, 1983, 5 (05) :361-364

[25] Highly controlled acetylene accommodation in a metal-organic microporous material [J].

Matsuda, R ;

Kitaura, R ;

Kitagawa, S ;

Kubota, Y ;

Belosludov, RV ;

Kobayashi, TC ;

Sakamoto, H ;

Chiba, T ;

Takata, M ;

Kawazoe, Y ;

Mita, Y .

NATURE, 2005, 436 (7048) :238-241

[26] Influence of the anion on the coordination mode of an unsymmetrical N-heterocyclic ligand in Cd(II) complexes: From discrete molecule to one- and two-dimensional structures [J].

Meng, Xiang-Ru ;

Wu, Xin-Juan ;

Li, Da-Wei ;

Hou, Hong-Wei ;

Fan, Yao-Ting .

POLYHEDRON, 2010, 29 (13) :2619-2628

[27] Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature [J].

Millward, AR ;

Yaghi, OM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (51) :17998-17999

[28] From molecules to crystal engineering: Supramolecular isomerism and polymorphism in network solids [J].

Moulton, B ;

Zaworotko, MJ .

CHEMICAL REVIEWS, 2001, 101 (06) :1629-1658

[29] Synthesis and characterization of N -(alky(aryl)carbamothioyl)cyclohexanecarboxamide derivatives and their Ni(II) and Cu(II) complexes [J].

Ozer, Cemal Koray ;

Arslan, Hakan ;

Vanderveer, Don ;

Binzet, Gun .

JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (02) :266-276

[30] Unprecedented helix-based microporous metal-organic frameworks constructed from a single ligand [J].

Sang, Rui-Li ;

Xu, Li .

CHEMICAL COMMUNICATIONS, 2008, (46) :6143-6145

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