Thiol-epoxy 'click' polymerization: efficient construction of reactive and functional polymers

被引：125

作者：

Braendle, Andreas ^{[1
]}

Khan, Anzar ^{[1
]}

机构：

[1] ETH, Swiss Fed Inst Technol, Dept Mat, CH-8093 Zurich, Switzerland

来源：

POLYMER CHEMISTRY | 2012年 / 3卷 / 12期

关键词：

CHEMISTRY;

D O I：

10.1039/c2py20591b

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The thiol-epoxy 'click' process is employed as a polymerization reaction to prepare linear polymer chains substituted with free hydroxyl groups. Post-polymerization modification of the hydroxyl units afforded functional polymers exhibiting substituent dependent properties. In this way, functionalized macromolecules are obtained in two simple synthetic steps from commercially available monomer building blocks and reagents.

引用

页码：3224 / 3227

页数：4