Synthesis, properties, and crystal structure of barium 1-oxyethylidenediphosphonatohydroxogermanate(IV) polyhydrate Ba3[Ge(μ-OH)(μ-Oedph)]6 • 25H2O

被引：3

作者：

Sergienko, V. S. ^{[1
]}

Seifullina, I. I. ^{[2
]}

Martsinko, E. E. ^{[2
]}

Ilyukhin, A. B. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[2] Mechnikov Natl Univ, UA-65082 Odessa, Ukraine

来源：

CRYSTALLOGRAPHY REPORTS | 2013年 / 58卷 / 02期

关键词：

FEATURES; ACID;

D O I：

10.1134/S1063774513010100

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The barium salt of 1-oxyethylidenediphosphonatohydroxogermanium acid Ba-3[Ge(mu-OH)(mu-Oedph)](6) center dot 25H(2)O (I) (H(4)Oedph is 1-oxyethylidenediphosphonic acid) was synthesized and studied by X-ray diffraction. The complex was characterized by elemental analysis, thermogravimetry, and IR spectroscopy. The hexanuclear cyclic complex anions [Ge(mu-OH)(mu-Oedph)] (6) (6-t-) ] cations, and water molecules of crystallization are the structural units of the crystal of I.

引用

页码：237 / 240

页数：4

共 9 条

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