Palladium nanoparticles supported on Fe3O4/amino acid nanocomposite: Highly active magnetic catalyst for solvent-free aerobic oxidation of alcohols

被引:51
作者
Zamani, Farzad [1 ,2 ]
Hosseini, Seyed Mohsen [1 ]
机构
[1] Islamic Azad Univ, Shahreza Branch, Dept Chem, Shahreza 31186145, Isfahan, Iran
[2] Isfahan Univ Technol, Lab Appl Chem, Esfahan 8415683111, Iran
关键词
Heterogeneous magnetic catalyst; Palladium nanoparticle; Cysteine amino acid; Solvent-free aerobic oxidation of alcohol; High selectivity; BENZYL ALCOHOL; MESOPOROUS SILICA; SIZE CONTROL; EFFICIENT; FERRITE; PD;
D O I
10.1016/j.catcom.2013.09.029
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, Fe3O4 nanoparticles were coated by a number of amino acids, e.g. cysteine, serine, glycine and beta-alanine, via a simple method. Because of the surface modification of the magnetic nanoparticles with amino acid, the obtained magnetic nanocomposite is able to trap palladium nanoparticles through a strong interaction between the metal nanoparticles and the functional groups of amino acids. Among the synthesized nanocomposites, Fe3O4/cysteine-Pd exhibited the highest catalytic performance and excellent selectivity in the solvent-free aerobic oxidation of various alcohols, along with high level of reusability. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:164 / 168
页数:5
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