Light-induced transformations of 1,2-dihydroquinolines: opening of the heterocycle, radical formation and photoinduced proton transfer

被引：6

作者：

Nekipelova, T. D. ^{[1
]}

Kuzmin, V. A. ^{[1
]}

机构：

[1] Russian Acad Sci, NM Emanuel Inst Biochem Phys, Moscow 119334, Russia

来源：

RUSSIAN CHEMICAL REVIEWS | 2012年 / 81卷 / 11期

关键词：

SODIUM DODECYL-SULFATE; LASER FLASH-PHOTOLYSIS; N; N-TETRAMETHYLBENZIDINE CATION; OXIDATION-PRODUCTS; ELECTRON-TRANSFER; EXCITED-STATES; AB-INITIO; WATER; 7-HYDROXYQUINOLINE; MECHANISM;

D O I：

10.1070/RC2012v081n11ABEH004293

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three types of light-induced photochemical reactions of 1,2-dihydroquinolines, opening of the heterocycle, formation of aminyl radicals upon the homolytic NH bond cleavage and proton transfer in protic solvents, have been considered. Special attention has been focused on the photoinduced proton transfer reactions. The effect of the dihydroquinoline structure and solvent composition on the routes and kinetic parameters of photochemical reactions has been analyzed. The bibliography includes 108 references.

引用

页码：983 / 993

页数：11

共 108 条

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