Bimetallic complexes of a potentially pentadentate, acyclic, symmetrical compartmental Schiff base ligand that provides suitable topology for an exogenous bridge

被引：26

作者：

Naik, AD ^{[1
]}

Annigeri, SM ^{[1
]}

Gangadharmath, UB ^{[1
]}

Revankar, VK ^{[1
]}

Mahale, VB ^{[1
]}

机构：

[1] Karnatak Univ, Dept Chem, Dharwad 580003, Karnataka, India

来源：

TRANSITION METAL CHEMISTRY | 2002年 / 27卷 / 03期

关键词：

D O I：

10.1023/A:1014886422227

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The binucleating ligand LH3, 2,6-diformyl-p-cresol-bis(phenylthioacetyldrazone), a Schiff base condensation product of 2,6-diformyl-p-cresol and phenylthioacetyldrazide forms complexes of the [M2ClL] type with Co-II,Co- Ni-II and Cu-II ions, which were characterized by elemental analysis, magnetic susceptibility, electronic spectra, molar conductance, i.r., n.m.r., e.p.r., t.g. and FAB mass spectral measurements. Sub-normal magnetic moments indicate the operation of antiferromagnetic coupling between the metal centres. The ligand and its copper complex show a pronounced fungistatic activity.

引用

页码：333 / 336

页数：4

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