Heterogeneously Catalyzed Efficient Oxygenation of Primary Amines to Amides by a Supported Ruthenium Hydroxide Catalyst

被引：156

作者：

Kim, Jung Won ^{[1
]}

Yamaguchi, Kazuya ^{[1
]}

Mizuno, Noritaka ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 48期

关键词：

amides; heterogeneous catalysis; oxygenation; ruthenium; sustainable chemistry;

D O I：

10.1002/anie.200802464

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Supporting green chemistry: The supported ruthenium hydroxide Ru(OH)x/Al2O3 acts as an efficient heterogeneous catalyst for the oxygenation of primary amines to primary amides (see scheme). Various primary amines (including aromatic, aliphatic, and heterocyclic) are converted in aqueous media, using air as the sole oxidant and producing only water as a by-product. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9249 / 9251

页数：3

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