Infrared study of the broken symmetry ground states in η-Mo4O11

被引:3
作者
Zhu, Z [1 ]
Musfeldt, JL
Wang, YJ
Sarrao, J
Fisk, Z
Negishi, H
Inoue, M
机构
[1] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA
[2] Natl High Magnet Field Lab, Tallahassee, FL USA
[3] Hiroshima Univ, Grad Sch Adv Sci Matter, Higashihiroshima 7398526, Japan
基金
美国国家科学基金会;
关键词
metal-insulator phase transition; structural phase transition; magnetic measurements; infrared and Raman spectroscopy;
D O I
10.1016/S0379-6779(98)00283-5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report far-infrared transmission measurements of eta-Mo4O11 at temperatures above and below the two charge-density-wave (CDW) transitions at 109 and 35 K. We analyze the exotic splitting patterns of the vibrational features in terms of the nature of the structural distortions, Data on Y-Mo4O11 is also shown to compare with the eta-phase material. Preliminary far-infrared reflectance spectra of eta-Mo4O11 taken in the presence of an external magnetic field is also presented.
引用
收藏
页码:2238 / 2241
页数:4
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