The magnetic properties of BaCo0.5Ni0.5F4

The family of BaMF4 with M of magnetic 3d transition metal ions is the typical multiferroic material. Pure phase solid solution of BaCoF4 and BaNiF4 with molar ratio of 1: 1 (BaCo0.5Ni0.5F4) is prepared by solid state reaction, which has been confirmed by X ray diffraction patterns. Field dependent magnetization measurements only show the linear curve with temperature down to 5 K, indicating the antiferromagnetic nature. Compared with BaCoF4 and BaNiF4, no significant enhancement of magnetization is observed, indicating the absence of ferrimagnetism and the random distribution of Co and Ni ions. The low temperature magnetic anomalies are studied by zero field cooled (ZFC) and field cooled (FC) temperature dependent magnetization (M-T) measurements. A bifurcation between FC and ZFC M-T curves happens at 118 K, indicating the onset of 2-dimensional antiferromagnetism. The magnetization maximum at 87 K is attributed to the 2-dimensional antiferromagnetic clusters, followed by the drastic decrease of magnetization, which is due to the onset of 3-dimensional antiferromagnetism. A dip is observed in FC M-T curve at 40 K, which is attributed to the 3-dimensional antiferromagnetic clusters. A drastic increase of magnetization is observed at 9 K, which is due to the uncompensated isolated spins. Exchange bias is clearly observed, with blocking temperature of 90 K. The contribution from surface spin glass has been excluded by the AC magnetization measurements, and the mechanism has been explained by the exchange coupling between the two antiferromagnetic phases. (C) 2018 Elsevier B.V. All rights reserved.