Dibromomanganese(II) complexes with hexamethylphosphoramide and phenylphosphonic bis(diamide) ligands

被引：19

作者：

Bortoluzzi, Marco ^{[1
,2
]}

Castro, Jesus ^{[3
]}

机构：

[1] Univ Ca Foscari Venezia, Dipartimento Sci Mol & Nanosistemi, Venice, VE, Italy

[2] CIRCC, Bari, Italy

[3] Univ Vigo, Fac Quim, Dept Quim Inorgan, Edificio Ciencias Expt, Vigo 36310, Galicia, Spain

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2019年 / 72卷 / 02期

关键词：

Manganese(II); tetrahedral complexes; phosphoramide ligands; phenylphosphonic diamide ligands; crystal structures; hydrogen bonds; INTERMOLECULAR INTERACTIONS; COPPER(I) COMPLEXES; CRYSTAL-STRUCTURE; HYDROGEN-BOND; LUMINESCENCE; TRIBOLUMINESCENCE; PHOSPHORAMIDE; VALIDATION; GEOMETRIES; ENERGIES;

D O I：

10.1080/00958972.2018.1560430

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetrahedral dibromomanganese(II) complexes having formulas [MnBr2{O = PR(NMe2)(2)}(2)] (R = NMe2 (1); Ph (2)) were isolated and characterized by single crystal X-ray diffraction. [MnBr2{O = P(NMe2)(3)}(2)] (1) crystallizes in the monoclinic C2/c space group. The asymmetric unit contains one half of the molecule with the Mn(II) atom in a distorted tetrahedral coordination. The intermolecular network of this coordination compound was studied by generating and inspecting its Hirshfeld surface, while the weak intramolecular hydrogen bonds were investigated computationally by AIM analysis in the gas phase and in solution. The Hirshfeld analysis was extended to the related [MnBr2{O = PPh(NMe2)(2)}(2)] complex (2). [GRAPHICS] .

引用

页码：309 / 327

页数：19

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