Hybrid thiol-ene network nanocomposites based on multi(meth) acrylate POSS

被引：50
作者：
Li, Liguo [1 ]
Liang, Rendong [1 ]
Li, Yajie [1 ]
Liu, Hongzhi [1 ]
Feng, Shengyu [1 ]
机构：
[1] Shandong Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Special Funct Aggregated Mat, Jinan 250100, Peoples R China
来源：
JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2013年 / 406卷
基金：
中国国家自然科学基金;
关键词：
POSS; Thiol-ene reaction; FTIR; Hybrid networks; POLYHEDRAL OLIGOMERIC SILSESQUIOXANE; REACTION-DIFFUSION; POLYMERS; KINETICS; PHOTOPOLYMERIZATION; POLYMERIZATION; CAGES; REARRANGEMENT; CHEMISTRY; ROUTE;
D O I：
10.1016/j.jcis.2013.05.044
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
First, multi(meth)acrylate functionalized POSS monomers were synthesized in this paper. Secondly, FTIR was used to evaluate the homopolymerization behaviors of multi(meth)acrylate POSS and their copolymerization behaviors in the thiol-ene reactions with octa(3-mercaptopropyl) POSS in the presence of photoinitiator. Results showed that the photopolymerization rate of multimethacrylate POSS was faster than that of multiacrylate POSS. The FTIR results also showed that the copolymerizations were dominant in the thiol-ene reactions with octa(3-mercaptopropyl) POSS, different from traditional (meth)acrylatethiol system, in which homopolymerizations were predominant. Finally, the resulted hybrid networks based on POSS were characterized by XRD, FE-SEM, DSC, and TGA. The characterization results showed that hybrid networks based on POSS were homogeneous and exhibited high thermal stability. (C) 2013 Elsevier Inc. All rights reserved.
引用
收藏
页码：30 / 36
页数：7
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