Post-Hadean transitions in Jack Hills zircon provenance: A signal of the Late Heavy Bombardment?

Hadean Jack Hills (Western Australia) detrital zircons represent the best documented terrestrial resource with which to observe the pre-4 Ga Earth. The >4 Ga component of this semi-continuous 4.38 to 3.0 Ga zircon record has been investigated in detail for age, delta O-18, Lu-Hf systematics, and Ti thermometry. The more abundant post-Hadean population is less well-characterized, but a previous study (Bell et al., 2011) suggests a more restricted range of delta O-18 source materials together with a ca. 4.0-3.6 Ga discontinuity in Lu-Hf evolution. These differences could reflect a transformation in the character of the older zircon source region or their sourcing from different terranes entirely. The relative scarcity of 4.0-3.6 Ga zircons corresponds to a discontinuity in Lu-Hf evolution after which Hf-176/Hf-177 in zircon reverts to more radiogenic values relative to the >4 Ga population. We present new oxygen isotope, titanium, and trace element results for 4.0-3.6 Ga Jack Hills zircons in a search for apparent transitions in petrological conditions. Post-3.8 Ga zircons show a marked decrease in the occurrence of heavy oxygen ( > 6.5 parts per thousand), but remain close to the average of the Hadean distribution despite their restricted range. This may point to the decreased importance of sedimentary materials in post-3.8 Ga magmas. Ca. 3.9 Ga zircons fall into two categories: "Group I" displays temperatures and compositions similar to the Hadean zircons whereas "Group II" zircons have higher U and Hf, and lower (Th/U), Ce and P. Group II zircons also have anomalously low Ti, and are remarkably concordant in the U-Pb system. Group II's geochemical characteristics are consistent with formation by transgressive recrystallization (Hoskin and Black, 2000), in which non-essential structural constituents are purged during high-grade thermal metamorphism. The restricted age range of Group II occurrence (3.91-3.84) and its coincidence with the postulated intense bolide flux in the inner solar system (i.e., Late Heavy Bombardment; 3.95-3.85) may have causal significance. (C) 2013 Elsevier B.V. All rights reserved.