Catalytic Hydrogen Oxidation: Dawn of a New Iron Age

被引：46

作者：

Simmons, Trevor R. ^{[1
]}

Artero, Vincent ^{[1
]}

机构：

[1] Univ Grenoble 1, CEA, CNRS, Lab Chem & Biol Met, F-38054 Grenoble 9, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 24期

基金：

欧洲研究理事会;

关键词：

bioinorganic chemistry; homogeneous catalysis; hydrides; hydrogen; hydrogenases; NIFE HYDROGENASES; ACTIVE-SITE; H-2; COMPLEXES; ELECTROCATALYSTS; RELEVANT; ELECTRON; MODELS;

D O I：

10.1002/anie.201302908

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One metal or two? Recent results in the design of hydrogenase mimics have resulted in NiFe- and Fe-based complexes (see picture) that split molecular H2 into electrons and protons. Although these compounds are still far from technological application they improve our understanding of how nature exploits abundant metals to achieve complex reactions. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6143 / 6145

页数：3

共 29 条

[1] Hydride-Containing Models for the Active Site of the Nickel-Iron Hydrogenases [J].

Barton, Bryan E. ;

Rauchfuss, Thomas B. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (42) :14877-14885

[2] Nickel-Iron Dithiolato Hydrides Relevant to the [NiFe]-Hydrogenase Active Site [J].

Barton, Bryan E. ;

Whaley, C. Matthew ;

Rauchfuss, Thomas B. ;

Gray, Danielle L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (20) :6942-+

[3] Direct detection of a hydrogen ligand in the [NiFe] center of the regulatory H2-sensing hydrogenase from Ralstonia eutropha in its reduced state by HYSCORE and ENDOR spectroscopy [J].

Brecht, M ;

van Gastel, M ;

Buhrke, T ;

Friedrich, B ;

Lubitz, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (43) :13075-13083

[4] Combining acid-base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase [J].

Camara, James M. ;

Rauchfuss, Thomas B. .

NATURE CHEMISTRY, 2012, 4 (01) :26-30

[5] Modelling NiFe hydrogenases: nickel-based electrocatalysts for hydrogen production [J].

Canaguier, Sigolene ;

Artero, Vincent ;

Fontecave, Marc .

DALTON TRANSACTIONS, 2008, (03) :315-325

[6] Catalytic hydrogen production by a Ni-Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step [J].

Canaguier, Sigolene ;

Fourmond, Vincent ;

Perotto, Carlo U. ;

Fize, Jennifer ;

Pecaut, Jacques ;

Fontecave, Marc ;

Field, Martin J. ;

Artero, Vincent .

CHEMICAL COMMUNICATIONS, 2013, 49 (44) :5004-5006

[7] Cp*--Ruthenium-Nickel-Based H2-Evolving Electrocatalysts as Bio-inspired Models of NiFe Hydrogenases [J].

Canaguier, Sigolene ;

Fontecave, Marc ;

Artero, Vincent .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (07) :1094-1099

[8] A structural and functional mimic of the active site of NiFe hydrogenases [J].

Canaguier, Sigolene ;

Field, Martin ;

Oudart, Yohan ;

Pecaut, Jacques ;

Fontecave, Marc ;

Artero, Vincent .

CHEMICAL COMMUNICATIONS, 2010, 46 (32) :5876-5878

[9] Cyclopentadienyl Ruthenium-Nickel Catalysts for Biomimetic Hydrogen Evolution: Electrocatalytic Properties and Mechanistic DFT Studies [J].

Canaguier, Sigolene ;

Vaccaro, Loredana ;

Artero, Vincent ;

Ostermann, Rainer ;

Pecaut, Jacques ;

Field, Martin J. ;

Fontecave, Marc .

CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (37) :9350-9364

[10] Enzymes as working or inspirational electrocatalysts for fuel cells and electrolysis [J].

Cracknell, James A. ;

Vincent, Kylie A. ;

Armstrong, Fraser A. .

CHEMICAL REVIEWS, 2008, 108 (07) :2439-2461

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