Crystal and molecular structures of salts of the secondary permethylmetallocenylmethyl cations (C5Me5MC5Me4CHR)+X- (M = Ru, Os; R = Ph, C6F5; X = BF4, PF6)

被引：3

作者：

Kreindlin, AZ ^{[1
]}

Suponitsky, KY ^{[1
]}

Dolgushin, FM ^{[1
]}

Starikova, ZA ^{[1
]}

Rybinskaya, MI ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2001年 / 50卷 / 09期

关键词：

ruthenium; osmium; permethylmetallocenylmethyl cations; X-ray diffraction analysis; NMR spectroscopy;

D O I：

10.1023/A:1013038602864

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structures of tetrafluoroborates of the secondary permethylmetallocenylmethyl cations [Cp*MC5Me4CHR](+) (Cp* = C5Me5; 1b; M = Ru Ph; 1e: M = Os, R = C6F5) were established by X-ray diffraction analysis. The angles of inclination (alpha) of the C(1)-C(11) bond coordinated to the metal atom with respect to the plane of the C5Me4 ligand are 31.5degrees and 35.6degrees, and the M-C(11) distances are 2.506 and 2.401 Angstrom in 1b,c, respectively.

引用

页码：1616 / 1619

页数：4

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