Crystal and molecular structures of salts of the secondary permethylmetallocenylmethyl cations (C5Me5MC5Me4CHR)+X- (M = Ru, Os; R = Ph, C6F5; X = BF4, PF6)

被引：3
|
作者：
Kreindlin, AZ [1 ]
Suponitsky, KY [1 ]
Dolgushin, FM [1 ]
Starikova, ZA [1 ]
Rybinskaya, MI [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2001年 / 50卷 / 09期
关键词：
ruthenium; osmium; permethylmetallocenylmethyl cations; X-ray diffraction analysis; NMR spectroscopy;
D O I：
10.1023/A:1013038602864
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structures of tetrafluoroborates of the secondary permethylmetallocenylmethyl cations [Cp*MC5Me4CHR](+) (Cp* = C5Me5; 1b; M = Ru Ph; 1e: M = Os, R = C6F5) were established by X-ray diffraction analysis. The angles of inclination (alpha) of the C(1)-C(11) bond coordinated to the metal atom with respect to the plane of the C5Me4 ligand are 31.5degrees and 35.6degrees, and the M-C(11) distances are 2.506 and 2.401 Angstrom in 1b,c, respectively.
引用
收藏
页码：1616 / 1619
页数：4
相关论文
共 50 条
12345